Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Peter D. Metelski"'
Autor:
Peter D. Metelski
Publikováno v:
Industrial Arene Chemistry. :2101-2115
Autor:
Casey Hetrick, Mark R. Nimlos, Glen Allen Ferguson, Kimberly A. Magrini-Bair, Michael Talmadge, Stefan Czernik, Thomas D. Foust, Robert M. Baldwin, Robert L. McCormick, Gregg T. Beckham, Mary J. Biddy, Peter D. Metelski
Publikováno v:
Green Chem.. 16:407-453
Pyrolysis offers a rapid and efficient means to depolymerize lignocellulosic biomass, resulting in gas, liquid, and solid products with varying yields and compositions depending on the process conditions. With respect to manufacture of “drop-in”
A spray reactor concept for catalytic oxidation of p-xylene to produce high-purity terephthalic acid
Publikováno v:
Chemical Engineering Science. 104:93-102
A spray reactor in which the liquid phase containing dissolved p-xylene (pX) and the catalyst is dispersed as fine droplets by a nozzle into a continuous vapor phase containing the oxidant (O2) is shown to produce high-purity terephthalic acid (TPA)
Autor:
James H. Espenson, Peter D. Metelski
Publikováno v:
The Journal of Physical Chemistry A. 105:5881-5884
The dibromide radical (believed to be HBr2• in acetic acid) reacts with methylarenes, aldehydes, and carboxylic acids in acetic acid. The kinetics of these reactions were studied with the use of la...
Publikováno v:
Inorganic Chemistry. 40:3228-3233
The oxidation of hydrogen bromide and alkali metal bromide salts to bromine in acetic acid by cobalt(III) acetate has been studied. The oxidation is inhibited by Mn(OAc)(2) and Co(OAc)(2), which lower the bromide concentration through complexation. S
Publikováno v:
Inorganic Chemistry. 39:2434-2439
Different pathways for benzylic bromide transformations were examined under conditions of cobalt-bromide catalysis in acetic acid. It has been shown that benzylic bromides participate in the catalytic cycle through their catalyzed and noncatalyzed ox
Publikováno v:
Inorganic Chemistry. 38:3103-3109
Volumes of reaction ΔVAg/AgCl (vs Ag/AgCl/4.0 mol L-1 KCl) and of activation ΔVel⧧ for the electrode reactions of the aqueous Co(azacapten)3+/2+, Ru(en)33+/2+, and Co(tacn)23+/2+ couples have been measured by high-pressure cyclic and AC voltammet
Publikováno v:
Inorganic Chemistry. 38:301-307
Rate constants kex for the Os(CN)63-/4-, Mo(CN)83-/4-, and W(CN)83-/4- self-exchange reactions in aqueous solution have been measured by 13C NMR as functions of pressure, temperature, and added ele...
Publikováno v:
Canadian Journal of Chemistry. 73:61-69
The four-coordinate anion CuI(dpym)2− (Hdpym = 3,3′,5,5′-tetramethyl-4,4′-dicarboethoxydipyrromethene) can be prepared in solution in acetone either by electrochemical reduction of the known tetrahedral complex CuII(dpym)20 (E0 = −290 mV vs