Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Peter D. McDonnell"'
Publikováno v:
ChemInform. 22
Publikováno v:
Journal of Bioscience and Bioengineering. 108:S21
Autor:
Norris C. J. Chokotho, Peter D. McDonnell, Terence C. Jarvis, C. David Johnson, Colim C. Lewis, Mario E.Alva Astudillo
Publikováno v:
Tetrahedron. 41:5919-5928
The tautomerism between hydroxy Schiff bases, X-C6H4CR=NCMe2CH2OH (R=H, Me, C6H5; X is a range of substituents) and X-C6H4,CR=NC6H4 (o-CH2OH), and the corresponding ring closed systems, oxazolidines and dihydrobenzoxazines, has been investigated. In
Autor:
C. David Johnson, Peter D. McDonnell, Timothy A.P. Weatherstone, Jeremy P. Bradley, Terence C. Jarvis
Publikováno v:
Tetrahedron Letters. 24:2851-2854
The mechanistic criterion of reversed substituent effects in reactions, formally classified as 5-endo-trig and 6-endo-trig , is examined.
Publikováno v:
ChemInform. 20
The reaction constant ρ for the cyclization of (I) is found to ρ = -4.0 using substituent constants σ+.
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :957
The rates of cyclisation of 2-hydroxy-2-methyl-5-arylpent-4-yn-3-ones in trifluoroacetic acid are reported. An approximate ρ value of –4.0 (using σ+) and a kinetic isotope effect, KTFA/KTFA – d, of 4.2 are observed, which suggest that the react