Výsledky vyhledávání - "Perry M. Scheetz"

Synthesis, Structure, Dynamics, and Enantioface-Selective η3-Benzyl Coordination in the Chiral Rhodium Complexes Rh(diphos*)(η3-CH2Ph)

Autor: Curtis E. Moore, David S. Glueck, Arnold L. Rheingold, Russell P. Hughes, Sarah T. Chachula, Perry M. Scheetz, Milan Gembicky

Publikováno v: Organometallics. 39:3802-3816

The rhodium benzyl complexes Rh(diphos*)(η3-CH2Ph) (1–14, diphos* = chiral bis(phosphine)), potential precursors for asymmetric catalysis, were prepared either by treatment of Rh(COD)(η3-CH2Ph) (15...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c786b2e81664cbf00ecbee375a199213
https://doi.org/10.1021/acs.organomet.0c00516

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Oxidative addition of methylene chloride to Me-DuPhos complexes of palladium and rhodium

Autor: Perry M. Scheetz, Arnold L. Rheingold, Sarah K. Gibbons, David S. Glueck, Natalia F. Blank

Publikováno v: Inorganica Chimica Acta. 483:111-115

Oxidative addition of methylene chloride to Pd((R,R)-Me-DuPhos)(L) (1–3; L = P(t-Bu)3, PCy3, or trans-stilbene) gave Pd((R,R)-Me-DuPhos)(CH2Cl)(Cl) (4). Treatment of [Rh(COD)(Cl)]2 with (R,R)-Me-DuPhos at low temperature in THF or CH2Cl2 afforded [

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e91b16df7f3b262ae3af268d028ea5b6
https://doi.org/10.1016/j.ica.2018.08.007

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Rhodium-Catalyzed Isomerization of a Bis(secondary phosphine) to an Unsymmetrical Diphosphine via P–C Cleavage and P–P and C–H Bond Formation

Autor: David S. Glueck, Arnold L. Rheingold, Perry M. Scheetz

Publikováno v: Organometallics. 36:3387-3397

To develop Rh-catalyzed dehydrocoupling for stereocontrolled synthesis of P–P bonds, we prepared potential intermediates, chiral rhodium phosphine-phosphido complexes, and investigated their stoichiometric and catalytic transformations. Treatment o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d432e86a2feb595ca7b55749e5dcc848
https://doi.org/10.1021/acs.organomet.7b00515

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Biscyclometalated platinum complexes with thiophene ligands

Autor: Skylar J. Ferrara, Nicole Kfoury, Matteo Chierchia, Leila Duman, Ava Kreider-Mueller, Perry M. Scheetz, James Morris, Tedros A. Balema, Joseph M. Tanski, Craig M. Anderson, Michael A. Weinstein

Publikováno v: Journal of Organometallic Chemistry. 723:188-197

The reaction of [Pt 2 (CH 3 ) 4 ( μ -S(CH 3 ) 2 ) 2 ] with four equivalents of ligand C 4 H 3 SCH NCH 2 C 6 H 5 gives the platinum (II) complex [Pt{(C 4 H 2 S)CH NCH 2 C 6 H 5 } 2 ] with two cyclometalated CˆN ligands. [Pt{(C 4 H 2 S)CH NCH 2 C 6 H

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0a0d24fce8cb1816e4ba7f79e04344e7
https://doi.org/10.1016/j.jorganchem.2012.10.027

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Synthesis of amine-tagged metal–organic frameworks isostructural to MIL-101(Cr)

Autor: Perry M. Scheetz, Ricardo B. Ferreira, André Luiz Barboza Formiga

Publikováno v: RSC Advances. 3:10181

Materials that are isostructural to MIL-101(Cr) were obtained from partial replacement of terephthalic acid to 2-aminoterephthalic acid, a linker containing amine functionalities in the synthesis media. The produced materials were characterized by di

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b904a12f0d9167b569cbf59090e88675
https://doi.org/10.1039/c3ra23443f

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