Zobrazeno 1 - 10
of 40
pro vyhledávání: '"Pedro Villuendas"'
Publikováno v:
Molecules, Vol 16, Iss 4, Pp 3420-3432 (2011)
Propylene carbonate is shown to be an environmentally friendly and sustainable replacement for dichloromethane and acetonitrile in proline-catalysed a-hydrazinations of aldehydes and ketones. Enantioselectivities comparable to those obtained in conve
Externí odkaz:
https://doaj.org/article/f98f2c3b13a34de1800f3d7e054ff05c
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The Cu-mediated synthesis of tetrasubstituted olefins by the addition of an acetate group and a thiolate to an unactivated internal alkyne is described. The reaction is fully stereoselective, because only the E alkene is obtained. If the alkyne is as
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
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The synthesis of fused heterocycle-pyridinones has been achieved by oxidative coupling of N-unprotected primary heterocycle-amides with internal alkynes. The reaction, which is catalysed by Ru(II) and assisted by Cu(II), takes place through C–H and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a81b0f0955185a4cabc6fd00a36052f
http://hdl.handle.net/10261/184809
http://hdl.handle.net/10261/184809
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds
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Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds
Two processes, intra‐ and intermolecular, involving alkenes and alkynes, have been used as main synthetic tools for the synthesis and functionalization of amyriad of heterocycles, whose industrial and academic importance resides in the fact that th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::776c283d5e94f3c1f22f55a50c881d58
http://hdl.handle.net/10261/187597
http://hdl.handle.net/10261/187597
Autor:
Santiago García-Granda, Laura Roces, Hajar el Hajjouji, Eva Belmonte Sánchez, Esteban P. Urriolabeitia, Pedro Villuendas, María José Iglesias, Fernando López Ortiz
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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A C,S-cycloaurated complex based on an ortho-substituted phosphinothioic amide framework has been synthesized in high yield through tin(IV)-Au(III) transmetalation from the corresponding chlorodimethylstannyl derivative. The latter was prepared in a
Publikováno v:
Journal of CO2 Utilization. 2:24-28
The influence of volume to surface area ratio on the rate of synthesis of cyclic carbonates from five epoxides and CO2 catalysed by a bimetallic aluminium(salen) complex and tetrabutylammonium bromide in stirred batch reactors has been investigated.
Publikováno v:
The Journal of Organic Chemistry. 78:419-426
The effect of moderate temperatures (22-100 °C) and pressures (1-10 bar) on the synthesis of cyclic carbonates from epoxides and carbon dioxide catalyzed by a combination of bimetallic aluminum complexes and tetrabutylammonium bromide is investigate
Publikováno v:
ChemInform. 47
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
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Organic syntheses based on the activation of C–H bonds catalysed by transition metals (TM) are of great interest because new pathways can be designed that were not previously available. Of the numerous TMs, ruthenium has emerged as a powerful alter
Publikováno v:
Tetrahedron Letters. 53:2736-2740
Quaternary phosphonium salts can be used as cocatalysts for the conversion of epoxides and carbon dioxide into cyclic carbonates catalysed by bimetallic aluminium(salen) complexes at ambient temperature and one atmosphere pressure. The phosphonium gr