Synthetic Study toward Triterpenes from the Schisandraceae Family of Natural Products

Autor: Pavle Kravljanac, Edward A. Anderson

Publikováno v: Molecules, Vol 28, Iss 11, p 4468 (2023)

Triterpenoid natural products from the Schisandraceae family have long presented a significant synthetic challenge. Lancifodilactone I, a member of the family not previously synthesized, was identified as a key natural product target, from which many

Externí odkaz: https://doaj.org/article/5d53e51a403b40e4ab5b3be62023879f

Catalytic Synthesis of Trifluoromethylated Allenes, Indenes, Chromenes, and Olefins from Propargylic Alcohols in HFIP

Autor: Edward Richmond, Jing Yi, Pavle Kravljanac, Vuk D. Vuković, Joseph Moran, Florent Noël

Publikováno v: Journal of Organic Chemistry
Journal of Organic Chemistry, 2019, 84 (24), pp.15926-15947. ⟨10.1021/acs.joc.9b02398⟩
Journal of Organic Chemistry, American Chemical Society, 2019, 84 (24), pp.15926-15947. ⟨10.1021/acs.joc.9b02398⟩
The Journal of Organic Chemistry

A general method to access CF3-substituted allenes from propargylic alcohols under Lewis acid catalysis in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) as solvent is described. By tuning the reaction t...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::985ee51f69db09ca1f6b63f555812d4c
https://hal.science/hal-02516523