Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Pavan K. Vardhanapu"'
Autor:
Neha Jha, Anand Pariyar, Tahereh Sadat Parvini, Christian Denker, Pavan K. Vardhanapu, Gonela Vijaykumar, Arne Ahrens, Tobias Meyer, Michael Seibt, Nicolae Atodiresei, Jagadeesh S. Moodera, Swadhin K. Mandal, Markus Münzenberg
Publikováno v:
ACS applied electronic materials 5(3), 1471-1477 (2023). doi:10.1021/acsaelm.2c01428
Delocalized carbon-based radical species with unpaired spin, such as the phenalenyl (PLY) radical, have opened avenues for developing multifunctional organic spintronic devices. Using direct laser writing and in situ deposition, we successfully fabri
Autor:
Swadhin K. Mandal, Gonela Vijaykumar, Pradip Kumar Hota, Rameswar Bhattacharjee, Samaresh Chandra Sau, Ayan Datta, R. Govindarajan, Pavan K. Vardhanapu
Publikováno v:
Chemical Science. 10:1879-1884
This work demonstrates the first-ever completely metal-free approach to the capture of CO2 from air followed by reduction to methoxyborane (which produces methanol on hydrolysis) or sodium formate (which produces formic acid on hydrolysis) under ambi
Publikováno v:
Organometallics. 37:2602-2608
Herein we report the synthesis of a cyclic (alkyl)amino carbene (cAAC) complex of AlMe3. This complex was used as an efficient catalyst for the guanylation reaction of carbodiimides with primary arylamines and secondary amines to deliver guanidine de
Publikováno v:
Journal of Organometallic Chemistry. 865:51-57
We report synthesis of two new palladium(II) complexes of abnormal N-heterocyclic carbene ligands. The catalytic activity of these palladium(II) complexes was examined for the decarboxylative arylation of N-methylindole-carboxylic acids. An exclusive
Publikováno v:
Organometallics. 36:4753-4758
Herein we report the hydroheteroarylation of vinylarenes with benzoxazole in the presence of a free abnormal N-heterocyclic carbene and Ni(COD)2, resulting in 1,1-diarylethane products exclusively. In an attempt to understand the mechanism of this ca
Autor:
Pradip Kumar Hota, Gonela Vijaykumar, Samaresh Chandra Sau, Swadhin K. Mandal, Pavan K. Vardhanapu, Jasimuddin Ahmed, Sreejyothi P
Publikováno v:
European Journal of Organic Chemistry. 2017:1004-1011
Herein, we report a versatile catalytic system for the direct C–H arylation of heteroarenes with activated aryl chloride substrates. The catalyst works successfully for a variety of heteroarenes and aryl chloride coupling partners under very low ca
Autor:
Gonela Vijaykumar, Pavan K. Vardhanapu, Rameswar Bhattacharjee, Samaresh Chandra Sau, Ayan Datta, Swadhin K. Mandal
Publikováno v:
Angewandte Chemie. 128:15371-15375
An abnormal N-heterocyclic carbene (aNHC) based homogeneous catalyst has been used for the reduction of carbon dioxide to methoxyborane in the presence of a range of hydroboranes under ambient conditions and resulted in the highest turnover number of
Publikováno v:
Journal of Chemical Sciences. 128:613-620
Reactions of B(C6F5)3 with abnormal N-heterocyclic carbene (aNHC), L1 and cyclic (alkyl)(amino) carbene (cAAC), L2 in the presence of moisture as well as in its absence, have been investigated in toluene. Reaction of aNHC with 1 equivalent of B(C6F5)
Autor:
Anex Jose, Bikash Kumar Shaw, Jasimuddin Ahmed, Amita A. Mathews, Tamal K. Sen, Swadhin K. Mandal, Pavan K. Vardhanapu
Publikováno v:
The Journal of organic chemistry. 84(1)
Main group metal based catalysis has been considered to be a cost-effective alternative way to the transition metal based catalysis, due to the high abundance of main group metals in the Earth's crust. Among the main group metals, aluminum is the mos
Publikováno v:
The Journal of organic chemistry. 83(16)
This work describes the dehydrogenative coupling of heteroarenes using a dimeric halo-bridged palladium(II) catalyst bearing an abnormal NHC ( aNHC) backbone. The catalyst can successfully activate the C-H bond of a wide range of heteroarenes, which