Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Paula Dominguez-Molano"'
Publikováno v:
Advanced Science, Vol 11, Iss 16, Pp n/a-n/a (2024)
Abstract The present paper reports a remote carbon‐to‐carbon boryl migration via an intramolecular 1,4‐B/Cu shift, which establishes an in situ stereospecific electrophilic trap on the alkene moiety. The synthetic application is developed to pr
Externí odkaz:
https://doaj.org/article/a88b433d925440a68807fed80d815f6a
Publikováno v:
Angewandte Chemie International Edition.
Publikováno v:
European Journal of Inorganic Chemistry. 2021:2802-2813
Publikováno v:
Organic letters. 24(27)
Palladium catalyzes the cyclopropanation of 2-substituted 1,1-diborylalkenes with (trimethylsilyl)diazomethane. The relative stereoselectivity is controlled via a carbene insertion sequence generating an exclusive
Autor:
Paula Dominguez-Molano, Gerard Bru, Elena Fernández, Oriol Salvado, Jorge J. Carbó, Ricardo J. Maza
Publikováno v:
Chemical Communications. 57:13361-13364
Exchange of boryl moieties between alkenylboranes and diboron reagents has been postulated as a stereospecific cross-metathesis pathway with concomitant formation of mixed diboron reagents. DFT calculations propose a mechanism for the stereocontrolle