Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Paul S. Ammala"'
Autor:
Christopher M. Kepert, B.O. West, Leone Spiccia, Stuart Robert Batten, Adrian M. B. van den Bergen, Paul S. Ammala
Publikováno v:
Inorganica Chimica Acta. 353:75-81
The reaction of [Fe4(μ3-O)2(O2CPh)8(py)2] (1) with Ti(OPrn)4 in toluene yields separate Fe and Ti species each containing both carboxylate and alkoxide groups rather than a bimetallic FeTi complex. The addition of neopentanol to the reaction mixt
Autor:
Christopher M. Kepert, Boujemaa Moubaraki, John D. Cashion, Leone Spiccia, B.O. West, Keith S. Murray, Stuart Robert Batten, Paul S. Ammala
Publikováno v:
Inorganica Chimica Acta. 331:90-97
The reaction of an Fe(III) oxo-benzoate species (1) with Al(OR)3 (R=Pri, Busec) yields the hexanuclear derivatives [Fe6(μ3-O)2(OR)8(O2CPh)6] (R=Pri (2); R=Busec (3)) which consist of planar Fe4(μ3-O)2 units, formed by two Fe3(μ3-O) groupings havin
Autor:
B.O. West, Keith S. Murray, Leone Spiccia, Paul S. Ammala, John D. Cashion, Boujemaa Moubaraki, Christopher M. Kepert
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2032-2041
Reaction of [Fe3(μ3-O)(O2CPh)6(H2O)3](O2CPh) with pyridine yields a product (2) which on recrystallisation rearranges to [Fe6(μ-O)2(μ-OH)2(O2CPh)12(py)2] (3). Magnetic and Mossbauer spectral analyses suggest that compound (2) contains an Fe4(O)2 c