Výsledky vyhledávání - "Paul Niklas Ruth"

Akademický článek

Hirshfeld atom refinement based on projector augmented wave densities with periodic boundary conditions

Autor: Paul Niklas Ruth, Regine Herbst-Irmer, Dietmar Stalke

Publikováno v: IUCrJ, Vol 9, Iss 2, Pp 286-297 (2022)

Hirshfeld atom refinement (HAR) is an X-ray diffraction refinement method that, in numerous publications, has been shown to give H-atom bond lengths in close agreement with neutron diffraction derived values. Presented here is a first evaluation of a

Externí odkaz: https://doaj.org/article/ef4c9819e2df42e096458cbf52947a66

Zobrazit plný text záznamu

One silicon atom of bis(silylene) functions as a selective Lewis base under adduct formation with a Lewis acid

Autor: Yi Ding, Mohd Nazish, Paul Niklas Ruth, Regine Herbst-Irmer, Dietmar Stalke, Herbert W. Roesky

Publikováno v: Dalton Transactions. 52:6175-6179

We describe the facile and selective one-pot synthetic route to silylene-aluminum and silylene-gallium adducts, in which one silicon atom of bis(silylene) functions as a selective Lewis base under adduct formation with a Lewis acid.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6121bab2f9956cd136080cf501544f77
https://doi.org/10.1039/d3dt00811h

Zobrazit plný text záznamu

A donor-supported silavinylidene and silylium ylides: boroles as a flexible platform for versatile Si(ii) chemistry

Autor: Julijan Sarcevic, Tobias Heitkemper, Paul Niklas Ruth, Leonard Naß, Maximilian Kubis, Dietmar Stalke, Christian P. Sindlinger

Publikováno v: Chemical Science. 14:5148-5159

Boroles react with a nucleophilic silylene to give silylium ylides or bicyclic sila-borabicyclo[2.1.1]hex-2-ene. Reduction either affords clusters of Si(ii) or a donor-supported silavinylidene, which can be subsequently converted into the former.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1efdb2d57e77a473baabe6516e7b2966
https://doi.org/10.1039/d3sc00808h

Zobrazit plný text záznamu

Stabilization of Reactive Nitrene by Silylenes without Using a Reducing Metal

Autor: Samir Kumar Sarkar, Shahila Muhammed, Daniel Lüert, Pattiyil Parameswaran, Mohd Nazish, Dietmar Stalke, Zhi Yang, Paul Niklas Ruth, Christina M. Legendre, Herbert W. Roesky, Regine Herbst-Irmer, Yi Ding

Publikováno v: Angewandte Chemie International Edition. 60:27206-27211

Herein, we report the stabilization of nitrene reagents as the source of a nitrogen atom to synthesize nitrogen-incorporated R1 LSi-N←SiLR2 (1) [L=PhC(NtBu)2 ; R1 =NTMS2 , R2 =NTMS]. Compound 1 is synthesized by reacting LSi(I)-SiI L with 3.1 equiv

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::83e9df6e3dbe4228f5399b558a77e9fd
https://doi.org/10.1002/anie.202110456

Zobrazit plný text záznamu

Trapping x‐ray radiation damage from homolytic Se–C bond cleavage in BnSeSeBn crystals (Bn=benzyl, CH2C6H5)

Autor: Christian J. Schürmann, Thorsten L. Teuteberg, A. Claudia Stückl, Paul Niklas Ruth, Fabian Hecker, Regine Herbst‐Irmer, Ricardo A. Mata, Dietmar Stalke

Publikováno v: Angewandte Chemie International Edition

Irradiation of dibenzyl diselenide BnSeSeBn with X-ray or UV-light cleaves the Se-C and the Se-Se bonds, inducing stable and metastable radical states. They are inevitably important to all natural and life sciences. Structural changes due to X-ray-in

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::075463a6d03c955a2d48ee10c2e8f6fa
https://hdl.handle.net/21.11116/0000-000B-338C-E21.11116/0000-000A-65B6-7

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání