Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Paul J. Foth"'
Publikováno v:
Journal of the American Chemical Society. 141:18944-18948
Primary amine products have been prepared using zirconium-catalyzed hydroaminoalkylation of alkenes with N-silylated benzylamine substrates. Catalysis using commercially available Zr(NMe2)4 affords an alternative disconnection to access α-arylated p
Publikováno v:
Chemical Science. 10:10331-10335
Herein, we report a new method for the one-pot synthesis of 1,1-dihydrofluoroalkyl sulfides by bubbling sulfuryl fluoride (SO2F2) through a solution of the corresponding alcohol and thiol. The reaction proceeds through a new class of bis(1,1-dihydrof
Tetrahydrocannabinol acid (THCA) and cannabidiol acid (CBDA), the two crucial organic components in cannabis and hemp, decarboxylate at different rates to their more active neutral forms. Theoretical calculations are used herein to analyze how the re
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8cb1a76afba31c4814406170af266e57
https://doi.org/10.26434/chemrxiv.12909887
https://doi.org/10.26434/chemrxiv.12909887
Xenon Difluoride Mediated Fluorodecarboxylations for the Syntheses of Di- and Trifluoromethoxyarenes
Autor:
Benjamin R. Boswell, Claire Chatalova-Sazepin, Maxim Epifanov, Glenn M. Sammis, Meruyert Binayeva, Manu Jagdeo, Carolyn Amador, Paul J. Foth, Wei Zhang
Publikováno v:
Organic Letters. 18:4570-4573
XeF2 is demonstrated to be a more proficient fluorine-transfer reagent than either NFSI or Selectfluor in fluorodecarboxylations of both mono- and difluoroaryloxy acetic acid derivatives. This method efficiently converts a wide range of neutral and e
Autor:
Paul J. Foth, Maxim Epifanov, Carolyn S. Higman, Jason E. Hein, Frances Gu, Charlotte Barrillon, Glenn M. Sammis, Sahil S. Kanani
Publikováno v:
Journal of the American Chemical Society. 140(48)
Sulfuryl fluoride, SO2F2, has been known and used as a fumigant for over 50 years but it has only recently gained widespread interest as a reagent for organic synthesis. Herein we report a novel application of sulfuryl fluoride gas in a new 1,1-dihyd