Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Patrik A. Runeberg"'
Publikováno v:
Molecules, Vol 25, Iss 5, p 1160 (2020)
Epoxidation of the C=C double bond in unsaturated norlignans derived from hydroxymatairesinol was studied. The intermediate epoxides were formed in up to quantitative conversions and were readily further transformed into tetrahydrofuran, aryltetralin
Externí odkaz:
https://doaj.org/article/e26ca6c297cf48e68d24cb3b2bffd591
Publikováno v:
Molecules, Vol 24, Iss 2, p 300 (2019)
Numerous oxidative transformations of lignan structures have been reported in the literature. In this paper we present an overview on the current findings in the field. The focus is put on transformations targeting a specific structure, a specific re
Externí odkaz:
https://doaj.org/article/769611fe48024fdd94c503d16d0b3520
Publikováno v:
Chemistry of Heterocyclic Compounds. 56:949-952
Improved methods for one-pot propargylation and Claisen rearrangement have been devised for natural lignans – matairesinol and α-conidendrin. The rearrangement was regiospecific, yielding only 2-methylbenzofuran derivatives.
Autor:
Patrik A Runeberg, Patrik Eklund
Publikováno v:
Organic Letters
Aerobic Pd(AcO)2/pyridine-catalyzed oxidation of unprotected carbohydrate-based terminal alkenes was studied. In accordance with previous reports, the initial reaction step gave methyl ketones. However, our substrates partially gave subsequent α,β-