Zobrazeno 1 - 10
of 23
pro vyhledávání: '"Patrick J. Roach"'
Autor:
Hyun Ji Julie Lee, Bingbing Wang, Sergey A. Nizkorodov, Peter A. Eckert, Julia Laskin, Qichi Hu, Patrick J. Roach, Alexander Laskin, Mary K. Gilles
Publikováno v:
Environmental Science & Technology. 48:12047-12055
Complementary methods of high-resolution mass spectrometry and microspectroscopy were utilized for molecular analysis of secondary organic aerosol (SOA) generated from ozonolysis of two structural monoterpene isomers: D-limonene SOA (LSOA) and α-pin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6404a5253b60a452d51bb4187b85145a
https://doi.org/10.1021/es503432r
https://doi.org/10.1021/es503432r
Autor:
Jeramie D. Watrous, Pieter C. Dorrestein, Julia Laskin, Theodore Alexandrov, Brandi S. Heath, Patrick J. Roach
Publikováno v:
Analytical Chemistry; Vol 85
Understanding molecular interaction pathways in complex biological systems constitutes a treasure trove of knowledge that might facilitate the specific, chemical manipulation of the countless microbiological systems that occur throughout our world. H
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::80cd1a6d255a751802f3007d7985f583
Publikováno v:
The Journal of Physical Chemistry A. 116:8085-8091
Understanding the emergence of properties from the size-selective cluster regime to larger nanoparticles is one of the principal goals of nanoscience. We have measured the size-selective reactivity of aluminum cluster anions with alcohols. All cluste
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a65b8f6621b6764c2b6a67123f08ec1a
https://doi.org/10.1021/jp3047196
https://doi.org/10.1021/jp3047196
Publikováno v:
Analytical Chemistry. 83:4924-4929
Higher-order mass defect analysis is introduced as a unique formula assignment and visualization method for the analysis of complex mass spectra. This approach is an extension of the concepts of Kendrick mass transformation widely used for identifica
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::45344528c7bba7ed5c6a0a93bfef933f
https://doi.org/10.1021/ac200654j
https://doi.org/10.1021/ac200654j
Publikováno v:
The Journal of Physical Chemistry A. 114:6071-6081
The reactivity of aluminum anion clusters with water was found to exhibit variations with size, with some clusters exhibiting negligible reactivity, others absorbing one or more water, while even others releasing H(2) with addition of multiple waters
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9cbe271c522081423383f1ff1501b0e4
https://doi.org/10.1021/jp911136s
https://doi.org/10.1021/jp911136s
Autor:
Sergey A. Nizkorodov, Julia Laskin, Gordon W. Slysz, Lucas Q. Nguyen, Gordon A. Anderson, Patrick J. Roach, Alexander Laskin, David L. Bones
Publikováno v:
Analytical Chemistry. 82:2048-2058
Characterization of the chemical composition and chemical transformations of secondary organic aerosol (SOA) is both a major challenge and the area of greatest uncertainty in current aerosol research. This study presents the first application of deso
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6cf020e585746c9e7fda98e2e7d48603
https://doi.org/10.1021/ac902801f
https://doi.org/10.1021/ac902801f
Publikováno v:
Science. 323:492-495
The reactions of metal clusters with small molecules often depend on cluster size. The selectivity of oxygen reactions with aluminum cluster anions can be well described within an electronic shell model; however, not all reactions are subject to the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c12748c8a6b15c8045549ae2f3903309
https://doi.org/10.1126/science.1165884
https://doi.org/10.1126/science.1165884
Publikováno v:
Journal of the American Chemical Society. 129:16098-16101
It is shown that spin accommodation plays a determining role in the reactivity of aluminum based anion clusters with oxygen. Experimental reactivity studies on aluminum and aluminum-hydrogen clusters show variable reactivity in even electron systems
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11bdced44789888623713c2657ad57ca
https://doi.org/10.1021/ja075998d
https://doi.org/10.1021/ja075998d
Publikováno v:
Proceedings of the National Academy of Sciences. 104:14565-14569
The formation and oxygen etching of Al n H m − clusters are characterized in a flow reactor experiment with first-principles theoretical investigations to demonstrate the exceptional stability of Al 4 H 7 − . The origin of the preponderance of Al
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7f150410ba02b59d54d855c3d10714f3
https://doi.org/10.1073/pnas.0706613104
https://doi.org/10.1073/pnas.0706613104
Publikováno v:
Proceedings of the National Academy of Sciences. 103:18405-18410
We recently demonstrated that, in gas phase clusters containing aluminum and iodine atoms, an Al 13 cluster behaves like a halogen atom, whereas an Al 14 cluster exhibits properties analogous to an alkaline earth atom. These observations, together wi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::95ab83e9c11275f4fdede5694351c214
https://doi.org/10.1073/pnas.0608781103
https://doi.org/10.1073/pnas.0608781103