Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Patrick G. McCaw"'
Publikováno v:
European Journal of Organic Chemistry. 2016:1630-1650
This review focuses on the synthesis and reactivity of thioketone S-oxides (sulfines). Sulfines have been long established as being reactive intermediates of high interest and with potential for wide application in organic synthesis. The review will
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e504832f51d9cc322f454aa31e8022dc
https://doi.org/10.1002/ejoc.201501538
https://doi.org/10.1002/ejoc.201501538
Autor:
Simon E. Lawrence, Patrick G. McCaw, Anita R. Maguire, Stuart G. Collins, U. B. Rao Khandavilli
Synthetic methodology for the generation of novel 1,2,5-oxathiazole-S-oxides from cycloaddition of nitrile oxide dipoles with α-oxo sulfines generated in situ via the α-sulfinyl carbenes derived from α-diazosulfoxides is described. Experimental ev
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f903c605afc08f03f4d1664588f086c7
https://hdl.handle.net/10468/7494
https://hdl.handle.net/10468/7494
Autor:
Simon E. Lawrence, Kevin S. Eccles, Naomi M. Buckley, Anita R. Maguire, Stuart G. Collins, Patrick G. McCaw
Publikováno v:
The Journal of organic chemistry. 82(7)
Diazo transfer to beta–keto sulfoxides to form stable isolable alpha-diazo-beta-keto sulfoxides has been achieved for the first time. Both monocyclic and benzofused ketone derived beta-keto sulfoxides were successfully explored as substrates for di
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::594881e3dfdf4df78984edfd3ec128b5
https://pubmed.ncbi.nlm.nih.gov/28272889
https://pubmed.ncbi.nlm.nih.gov/28272889
Continuous-flow generation of α-diazosulfoxides results in a two- to three-fold increase in yields and decreased reaction times compared to standard batch synthesis methods. These high yielding reactions are enabled by flowing through a bed of polys
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::325852f785d392790d8466086d7864c3
http://hdl.handle.net/10044/1/37069
http://hdl.handle.net/10044/1/37069
Publikováno v:
ChemInform. 47
This review focuses on the synthesis and reactivity of thioketone S-oxides (sulfines). Sulfines have been long established as being reactive intermediates of high interest and with potential for wide application in organic synthesis. The review will
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e83e6f7e4504aba72013d1269c6b5969
https://doi.org/10.1002/chin.201621248
https://doi.org/10.1002/chin.201621248