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pro vyhledávání: '"Patrick D. Hayes"'
Autor:
Ram S. Mohan, Ashvin R. Baru, Peter W. Anzalone, Mai P. Nguyen, Patrick D. Hayes, Russell C. Smith, Eric M. Danielson, Ambrose F. Panico
Publikováno v:
The Journal of Organic Chemistry. 70:2091-2096
[reaction: see text] Three one-pot methods for the conversion of aldehydes to homoallyl ethers catalyzed by Bi(OTf)(3).xH(2)O (1x4) have been developed. The one-pot synthesis of homoallyl ethers can be achieved either by in situ generation of the ace
Publikováno v:
Tetrahedron Letters. 44:9173-9175
Ketoximes undergo deprotection in CH 3 CN/acetone/H 2 O (3:6:1) in the presence of 20–40 mol% BiBr 3 /5 mol% Bi(OTf) 3 . Bismuth(III) salts are relatively non-toxic, insensitive to air and inexpensive. These features coupled with the use of a relat
Autor:
Ram S. Mohan, Mai P. Nguyen, Patrick D. Hayes, Ambrose F. Panico, Russell C. Smith, Ashvin R. Baru, Eric M. Danielson, Peter W. Anzalone
Publikováno v:
ChemInform. 36
Three one-pot methods for the conversion of aldehydes to homoallyl ethers catalyzed by Bi(OTf)3·xH2O (1 < x < 4) have been developed. The one-pot synthesis of homoallyl ethers can be achieved either by in situ generation of the acetal followed by it
Publikováno v:
ChemInform. 35
Aromatic aldehydes are smoothly converted into the corresponding acylals in good yields in the presence of 3–10 mol% Bi(NO3)3·5H2O. Ketones are not affected under the reaction conditions. The relatively non-toxic nature of the catalyst, its ease o