Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Patrice Nury"'
Publikováno v:
European Journal of Organic Chemistry. 2001:4137-4147
Benzaldehyde dimethylacetal (1) and 2-aryl-1,3-dioxolanes 5 react with organolithium reagents 2 in the presence of chiral ligands such as sparteine (3), 1-alkoxy-2-aminoethanes, or 1,2-dialkoxyethanes and BF3 to afford monosubstitution products in hi
Autor:
Patrice Nury, Paul Müller
Publikováno v:
Helvetica Chimica Acta. 84:662-677
The cyclohexene-derived aziridine 7-tosyl-7-azabicyclo[4.1.0]heptane (1) reacts with Grignard reagents in the presence of chiral nonracemic Cu-catalysts to afford sulfonamides 3a – e (Scheme 3) in up to 91% ee under optimized conditions (Table 2).
Publikováno v:
Helvetica Chimica Acta. 83:843-854
Treatment of (aR)‐[1,1′binaphthalene]‐8,8′‐diol ((−)‐1) with hexamethylphosphorous triamide afforded the N,N‐dimethylphosphoramidite (−)‐3 (Scheme 1). The synthesis of the analogous N,N‐diisopropylphosphoramidite 4 failed, howev
Autor:
Patrice Nury, Paul Müller and
Publikováno v:
Organic Letters. 1:439-442
Cyclohexene N-p-toluenesulfonylimine (1) undergoes enantioselective ring opening to 2b upon treatment with methylmagnesium halides or MeLi in the presence of chiral Cu-catalysts. No activation of the aziridine by Lewis acid is required. Enantioselect
Publikováno v:
Helvetica Chimica Acta, Vol. 82, No 6 (1999) pp. 935-945
Olefins undergo cyclopropanation with diphenylsulfonium (ethoxycarbonyl)methylide (=diphenylsulfonium 2‐ethoxy‐2‐oxoethylide; 3a) in the presence of chiral CuI or RhII catalysts. trans/cis Ratios and ee's of the cyclopropanes 6 obtained with th
Publikováno v:
Journal of Physical Organic Chemistry. 11:321-333
Transition metal-catalyzed decomposition of phenyliodonium and diphenylsulfonium ylides was in-vestigated with regard to application in asymmetric carbenoid reactions. Phenyliodonium ylides react in the presenceof Rh(II) catalysts with the same selec
Publikováno v:
Organic Process Research & Development. 8:663-665
The first safe and efficient synthesis of the important building block 2-amino-8-hydroxyquinoline (1) is described. Starting from the readily available N-oxide 3 of the cheap bulk chemical 8-hydroxyquinoline (2), the target compound is obtained in a
Publikováno v:
ChemInform. 29
Transition metal-catalyzed decomposition of phenyliodonium and diphenylsulfonium ylides was in-vestigated with regard to application in asymmetric carbenoid reactions. Phenyliodonium ylides react in the presenceof Rh(II) catalysts with the same selec
Publikováno v:
ChemInform. 30
Autor:
Patrice Nury, Paul Mueller
Publikováno v:
ChemInform. 30