Synthesis of 4‐Phosphinylpyrrolidin‐3‐ones via [3+2] Cycloaddition of Nitrones with Phosphinylallenes

Autor: Rayhane Hammami, Pascale Maldivi, Christian Philouze, Sébastien Carret, Benjamin Darses, Soufiane Touil, Jean‐François Poisson

Publikováno v: Advanced Synthesis & Catalysis. 365:1385-1390

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::44f7d4e730dced4d5935ab1d2bfdedee
https://doi.org/10.1002/adsc.202201386

Catalytic Nitrene Transfer by an Fe IV ‐Imido Complex Generated by a Comproportionation Process

Autor: Jordan Donat, Patrick Dubourdeaux, Martin Clémancey, Julia Rendon, Clara Gervasoni, Morgan Barbier, Jessica Barilone, Jacques Pécaut, Serge Gambarelli, Pascale Maldivi, Jean‐Marc Latour

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, In press, ⟨10.1002/chem.202201875⟩

International audience; Nitrene transfer reactions have emerged as one of the most powerful and versatile ways to insert an amine function to various kinds of hydrocarbon substrates. However, the mechanisms of nitrene generation have not been studied

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6b11d9cb0d525832a66d04cc12440ee0
https://doi.org/10.1002/chem.202201875

A Bioinspired NiII Superoxide Dismutase Catalyst Designed on an ATCUN-like Binding Motif

Autor: Olivier Proux, Pawel Guinard, Pascale Maldivi, Magali Douillard, Jacques Pécaut, Carole Duboc, Alan Le Goff, Jérémy Domergue, Colette Lebrun, Pascale Delangle

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 2021, 60 (17), pp.12772-12780. ⟨10.1021/acs.inorgchem.1c00899⟩

Nickel superoxide dismutase (NiSOD) is an enzyme that protects cells against O2·-. While the structure of its active site is known, the mechanism of the catalytic cycle is still not elucidated. Its active site displays a square planar NiII center wi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::285ec1fdd621e1fe6d2ae7bbb75c9afc
https://doi.org/10.1021/acs.inorgchem.1c00899

Photochromic dye-sensitized solar cells with light-driven adjustable optical transmission and power conversion efficiency

Autor: Renaud Demadrille, Antonio Riquelme, Juan A. Anta, Damien Joly, Frédéric Oswald, Valid Mwatati Mwalukuku, Stéphanie Narbey, Johan Liotier, Yann Kervella, Quentin Huaulmé, Pascale Maldivi

Publikováno v: Nat Energy
Nature Energy
Nature Energy, 2020, 5, pp.468-477. ⟨10.1038/s41560-020-0624-7⟩

Semi-transparent photovoltaics only allow for the fabrication of solar cells with an optical transmission that is fixed during their manufacturing resulting in a trade-off between transparency and efficiency. For the integration of semi-transparent d

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::eb8b07c70af4204ffe269f350f62ecce
https://pubmed.ncbi.nlm.nih.gov/35475116

Mononuclear Ni(II) Complexes with a S3O Coordination Sphere Based on a Tripodal Cysteine-Rich Ligand: pH Tuning of the Superoxide Dismutase Activity

Autor: Christelle Gateau, Pascale Maldivi, Pascale Delangle, Olivier Proux, Jérémy Domergue, Alan Le Goff, Jacques Pécaut, Carole Duboc, Colette Lebrun

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2019, 58 (19), pp.12775-12785. ⟨10.1021/acs.inorgchem.9b01686⟩
Inorganic Chemistry, 2019, 58 (19), pp.12775-12785. ⟨10.1021/acs.inorgchem.9b01686⟩

The superoxide dismutase (SOD) activity of mononuclear NiII complexes, whose structures are inspired by the NiSOD, has been investigated. They have been designed with a sulfur-rich pseudopeptide li...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1aa70f830780876ddcf0c401547610ab
https://doi.org/10.1021/acs.inorgchem.9b01686