Zobrazeno 1 - 10
of 136
pro vyhledávání: '"Pascale Crochet"'
Autor:
Pascale Crochet, Victorio Cadierno
Publikováno v:
Catalysts, Vol 13, Iss 2, p 436 (2023)
N-Heterocyclic carbenes (NHCs) are nowadays one of the most widely employed ligands in organometallic chemistry and homogeneous catalysis due to the inherent stability of the metal-carbene bond and the ease of modification of the backbone as well as
Externí odkaz:
https://doaj.org/article/54bc46f9d8e54c7fa6c970ce978d5317
Publikováno v:
Molbank, Vol 2021, Iss 2, p M1217 (2021)
The title compound, i.e., [RuCl2(η6-p-cymene)(PPh2NHnPr)] (2), was obtained in a 71% yield by reacting a toluene solution of the chlorophosphine complex [RuCl2(η6-p-cymene)(PPh2Cl)] (1) with two equivalents of n-propylamine at room temperature. The
Externí odkaz:
https://doaj.org/article/051ad6b5c83f42afb48a1a2540264d8f
Publikováno v:
Molbank, Vol 2021, Iss 2, p M1198 (2021)
The title compound was synthesized by electrophilic cyanation of commercially available (R)-4-chloro-α-methylbenzylamine with cyanogen bromide in diethyl ether, and isolated as a yellow oil in 84% yield. It was characterized by 1H and 13C{1H] NMR, I
Externí odkaz:
https://doaj.org/article/244aa9501eff4b42aa831a942b7d00df
Publikováno v:
Molbank, Vol 2020, Iss 1, p M1110 (2020)
The synthesis of a series of arene-osmium(II) complexes containing phosphinite-type ligands, namely, [OsCl2(η6-p-cymene){R2PO(CH2)nPh}] (R = Ph, n = 1 (4a), 2 (4b), 3 (4c); R = iPr, n = 1 (5a), 2 (5b), 3 (5c)) and [OsCl2(η6-benzene){iPr2PO(CH2)2Ph}
Externí odkaz:
https://doaj.org/article/2e3a86590c8540cc931189d5ada5355f
Autor:
Pascale Crochet, Victorio Cadierno
Publikováno v:
Inorganics, Vol 9, Iss 7, p 55 (2021)
Although the application of arene-osmium(II) complexes in homogeneous catalysis has been much less studied than that of their ruthenium analogues, different works have shown that, in some instances, a comparable or even superior effectiveness can be
Externí odkaz:
https://doaj.org/article/b3658b9be13d4a878a6b9df20b831a88
Publikováno v:
WOS:000665277500001
Molbank, Vol 2021, Iss M1198, p M1198 (2021)
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
Molbank, Vol 2021, Iss M1198, p M1198 (2021)
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
The title compound was synthesized by electrophilic cyanation of commercially available (R)-4-chloro-α-methylbenzylamine with cyanogen bromide in diethyl ether, and isolated as a yellow oil in 84% yield. It was characterized by 1H and 13C{1H] NMR, I
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5622c27b824d98781220322b3ed266c1
http://hdl.handle.net/10651/61684
http://hdl.handle.net/10651/61684
Autor:
Victorio Cadierno, Pascale Crochet
Publikováno v:
Scopus
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
Financial support by the Spanish Ministry of Economy, Industry and Competitiveness is acknowledged (MINECO project CTQ2016-75986-P).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0f046613b43c20fc3f4dde9c704d3382
http://hdl.handle.net/10651/61160
http://hdl.handle.net/10651/61160
Autor:
Daniel Álvarez, Pascale Crochet, M. Isabel Menéndez, Ramón López, Rebeca González-Fernández, Victorio Cadierno
Publikováno v:
Scopus
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
Digital.CSIC. Repositorio Institucional del CSIC
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
Digital.CSIC. Repositorio Institucional del CSIC
The synthesis of a large variety of ureas R1R2NC(O)NH2 (R1 and R2 = alkyl, aryl or H; 26 examples) was successfully accomplished by hydration of the corresponding cyanamides R1R2NCN using the phosphinous acid-based complexes [MCl2(η6-p-cymene)(PMe2O
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::030127cc3e88a67b6e45e28179cb95b9
http://hdl.handle.net/10651/57442
http://hdl.handle.net/10651/57442
Publikováno v:
Scopus
The catalytic hydration of nitriles and the rearrangement of aldoximes are atom-economical routes to generate primary amides of great academic and industrial interest. Among the different families of catalysts that have been developed for these trans
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60232ed91a83ba328bba6c8579dd8ecb
http://hdl.handle.net/10651/59240
http://hdl.handle.net/10651/59240
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(1)
The preparation of the tethered arene-ruthenium(II) complexes [RuCl2{η6:κ1(P)-C6H5(CH2)nOPR2}] (R = Ph, n = 1 (9a), 2 (9b), 3 (9c); R = iPr, n = 1 (10a), 2 (10b), 3 (10c)) from the corresponding phosphinite ligands R2PO(CH2)nPh (R = Ph, n = 1 (1a),