Sterically and Electronically Flexible Pyridylidene Amine Dinitrogen Ligands at Palladium: Hemilabile cis / trans Coordination and Application in Dehydrogenation Catalysis

Autor: Nicolas Lentz, Yanik Streit, Pascal Knörr, Martin Albrecht

Publikováno v: Chemistry – A European Journal. 28

Ligand design is crucial for the development of new catalysts and materials with new properties. Herein, the synthesis and unique hemilabile coordination properties of new bis-pyridylidene amine (bis-PYE) ligands to palladium, and preliminary catalyt

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cdc638eda84d5bd64e9590a6f3da358d
https://doi.org/10.1002/chem.202202672

Aerobic dehydrogenation of amines to nitriles catalyzed by triazolylidene ruthenium complexes with O2 as terminal oxidant

Autor: Pascal Knörr, Marta Olivares, Martin Albrecht

Publikováno v: Olivares, Marta; Knörr, Pascal; Albrecht, Martin (2020). Aerobic dehydrogenation of amines to nitriles catalyzed by triazolylidene ruthenium complexes with O2 as terminal oxidant. Dalton transactions, 49(6), pp. 1981-1991. Royal Society of Chemistry 10.1039/C9DT04873A

Pyridyl-substituted mesoionic triazolylidene ruthenium cymene complexes catalyze the oxidation of both aromatic and aliphatic amines to nitriles with high activity and selectivity under benign conditions using dioxygen as the terminal oxidant. Modifi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::249aac92a13b30ebb71a3d1caa338cee
https://boris.unibe.ch/141949/1/c9dt04873a-1.pdf