The Nature of P(σ ² λ ³ ↔σ ² λ ¹ ) Dualism: 3a,6a-Diaza-1,4-diphosphapentalene as a Form of Stabilized Singlet Phosphinidene.

Autor: Kornev AN; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia., Panova YS; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia., Sushev VV; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia., Dorado Daza DF; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia., Novikov AS; Saint Petersburg State University , 7/9 Universitetskaya Nab ., 199034 Saint Petersburg , Russia., Cherkasov AV; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia., Fukin GK; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia., Abakumov GA; G. A. Razuvaev Institute of Organometallic Chemistry , Russian Academy of Sciences , 49 Tropinin str. , 603137 Nizhny Novgorod , Russia.

Publikováno v: Inorganic chemistry [Inorg Chem] 2019 Dec 02; Vol. 58 (23), pp. 16144-16153. Date of Electronic Publication: 2019 Nov 15.

The intramolecular rearrangement of phosphinohydrazides [R'2P-NR-NR-M] → [RN═PR'2-NR-M]: general rules and exceptions. transformations of bulky phosphinohydrazines (R-NH-N(PPh2)2, R = tBu, Ph2P).

Autor: Kornev AN; Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 Tropinin Street, 603950 Nizhny Novgorod, Russia. akornev@iomc.ras.ru, Sushev VV, Panova YS, Belina NV, Lukoyanova OV, Fukin GK, Ketkov SY, Abakumov GA, Lönnecke P, Hey-Hawkins E

Publikováno v: Inorganic chemistry [Inorg Chem] 2012 Jan 16; Vol. 51 (2), pp. 874-81. Date of Electronic Publication: 2011 Dec 30.