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pro vyhledávání: '"Padraig C. Doolan"'
Publikováno v:
Chemischer Informationsdienst. 5
Autor:
Ja'far Al-Ka'bi, Peter H. Gore, David N. Waters, Robert Hollingworth, Jameel A. Farooqi, Padraig C. Doolan
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :501
The kinetics have been measured for the rearrangement of 1-phenylprop-2-en-1-ol (1) to 3-phenylprop-2-en-1-ol (2) in tetramethylene sulphone solution, catalysed by various tin(IV) chloride species. The rate coefficients, kn′ at 313.2 K, per unit co
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :241
In sulpholan solution 1-phenylprop-2-en-1-ol undergoes an anionotropic rearrangement to cinnamyl alcohol in the presence of metal and non-metal chloride Lewis acids. The rates of rearrangement are first order with respect to the alcohol, and are dire