Zobrazeno 1 - 10
of 40
pro vyhledávání: '"PK Grant"'
Publikováno v:
ChemInform. 22
Lewis acid treatment of a series of hydroxy epoxides promoted intramolecular nucleophilic epoxide opening to give hydroxy cyclic ethers. The regioselectivity of epoxide opening is controlled by a preference for SN2 attack at the more accessible epoxi
Publikováno v:
ChemInform. 24
The preparation of four epoxides (1)-(4) derived from manool [labda-8(17),14-dien-13-ol] and manoyl oxide (8,13-epoxylabdane) via diosphenols is reported. Lewis acid promoted intramolecular rearrangements of these were investigated. Reaction of epoxi
Autor:
PK Grant, G. P. Lynch
Publikováno v:
ChemInform. 24
A series of amino alkenes was synthesized from manool [labda-8(17),14-dien-13-ol] as substrates for an investigation of the ability of an amino group to act as an internal nucleophile during ozonolysis. A 10-membered ring keto lactam (20) was produce
Publikováno v:
ChemInform. 25
Publikováno v:
Australian Journal of Chemistry. 47:71
A novel ring opening of the acetal III (2) (8,13:13,17-diepoxy-14,15-dinorlabdane) with boron trifluoride/acetic anhydride led to the synthesis of acetals (16), (18)-(20) and (25)-(27) functionalized at C 12. The attempted ring opening of the hydroxy
Autor:
PK Grant, G. P. Lynch
Publikováno v:
Australian Journal of Chemistry. 46:49
A series of amino alkenes was synthesized from manool [labda-8(17),14-dien-13-ol] as substrates for an investigation of the ability of an amino group to act as an internal nucleophile during ozonolysis. A 10-membered ring keto lactam (20) was produce
Publikováno v:
Australian Journal of Chemistry. 46:1125
The preparation of four epoxides (1)-(4) derived from manool [labda-8(17),14-dien-13-ol] and manoyl oxide (8,13-epoxylabdane) via diosphenols is reported. Lewis acid promoted intramolecular rearrangements of these were investigated. Reaction of epoxi
Publikováno v:
Australian Journal of Chemistry. 44:897
The unsaturated lactone (2) derived from manool (1) has a particularly rigid 10-membered ring which gives rise to high asymmetric induction in epoxidation with m-chloroperoxybenzoic acid. The corresponding 11-membered lactone (14) shows greater flexi
Publikováno v:
Chemischer Informationsdienst. 9
The reactions of manool derivatives with sulfurated sodium borohydride to give sulfur-containing diterpene derivatives are reported. 13,17-Epithio-8,13-epoxy-14,15-dinorlabdane (12), the sulfur analogue of the highly odiferous compound 8,13:13,17-die
Publikováno v:
Australian Journal of Chemistry. 31:1791
Reaction of manool and its derivatives with ozone gave stable ozonides. The structure (6) of one of the ozonides isolated is of striking similarity to the perfumery acetals (1) and (2) derived from the potassium permanganate oxidation of manool (3).