Zobrazeno 1 - 10
of 239
pro vyhledávání: '"PETER G. SAMMES"'
Publikováno v:
Dyes and Pigments. 121:57-72
Isomeric equilbria of dinitro-substituted indolospirobenzopyrans, possessing 3′-gem-methyl- or 3′-cyclohexyl-substitutents, have been investigated using 1H NMR spectroscopy at six temperatures, ranging from 298 K to 410 K; isomerisation processes
Publikováno v:
Dyes and Pigments. 90:146-162
A series of novel 6-nitro substituted indolospirobenzopyrans are reported. The effects of substitution on their photoreversibility are investigated by: synthesising derivatives that possess sterically hindering (with regard to the spiropyran-opening
Publikováno v:
Dyes and Pigments. 83:31-50
Several, novel, 3′-, 5- and 3-substituted indolospirobenzopyrans were prepared and their reversible thermochromic equilibria were investigated by synthesising derivatives with appropriately placed “electronically” modifying substituents in both
Publikováno v:
Dyes and Pigments. 82:226-237
The photoreversibility of several novel indolospirobenzopyrans was investigated using temperature studies – monitored using 1H NMR spectroscopy, qualitative UV studies and acid deuterolysis (trifluorodeuterioacetic acid (TFA-D)) catalysed isomerisa
Publikováno v:
European Journal of Inorganic Chemistry. 2008:4951-4960
The photoreversible transportation of Zn 2+ ions across an interface using photochromic substituted-spirobenzopyrans has been demonstrated. The inclusion of strategically placed sterically influencing 3'-methyl-3b and 3-spirocyclohexyl-3c groupings i
Publikováno v:
Dyes and Pigments. 76:319-326
Following our publication of the synthesis of the new 5-substituted crowned spirocyclic benzopyrans ( 3a – c ), and the fact that suitably placed substituents can be used to influence their metal-ion chelating properties [Roxburgh, CJ, Sammes, PG.
Autor:
Peter G. Sammes, Craig J. Roxburgh
Publikováno v:
European Journal of Organic Chemistry. 2006:1050-1056
The reversible photochemical ion chelation of the newly synthesised substituted N,N′-bis(spiro[1-benzopyran-2,2′-indolyl])diazacrown systems 15a–c and the subsequent molecular electronic control of this process using appropriately placed substi
Autor:
Jason P. Cross, Peter G. Sammes
Publikováno v:
Journal of Luminescence. 110:101-111
Incorporation of the 2-(2-hydroxyphenyl)-pyridine system into aza-crown systems produces novel ligands for lanthanide ions and can act as sensitising antennae for terbium (III) ions.
Publikováno v:
Journal of Luminescence. 110:113-124
Titrations of the Lehn cryptand [Ln⊂bpy.bpy.bpy]3+ complexes of both europium (III) and terbium (III) with fluoride and phosphate ions indicate that these anions displace water from the solvation sphere. In the case of the europium complex an enhan
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 1. :1999-2005
Steric buttressing, using the removable trityl group as a protecting group for substituted allylamines, is used to effect selective cycloadditions and uncatalysed ene reactions under remarkably mild conditions.