Zobrazeno 1 - 10
of 292
pro vyhledávání: '"PER J. GAREGG"'
Publikováno v:
Carbohydrate Research. 337:2153-2159
Combination of a one-pot coupling technique and the use of benzyl ethers as permanent protecting groups offered a short and simple route to dioscin-type saponins. This strategy in combination with a mild reductive opening procedure of the spiroketal
Publikováno v:
Canadian Journal of Chemistry. 80:1105-1111
Using a linear assembly approach a highly differentially protected derivative of the common GPI-anchor core structure (α-D-Man-(1[Formula: see text]6)-α-D-Man-(1[Formula: see text]2)-α-D-Man-(1[Formula: see text]4)-α-D-GlcNH2-(1[Formula: see text
Publikováno v:
Tetrahedron. 58:1387-1398
Short synthetic routes to protected derivatives of 2-amino-2-deoxy-α- d -glucopyranosyl-(1→6)- d -myo-inositol are described. Various 2-azido-2-deoxy-glucosyl donors were synthesized, starting from d -glucal or glucosamine hydrochloride. Derivativ
Publikováno v:
The Journal of Organic Chemistry. 66:6234-6243
Spacer-equipped dimers and trimers of the repeating units of the capsular polysaccharide of Haemophilus influenzae type c, -4)-3-O-Ac-beta-D-GlcpNAc-(1--3)-alpha-D-Galp-(1-OPO(3-)-, and type f, -3)-beta-D-GalpNAc-(1--4)-3-O-Ac-alpha-D-GalpNAc-(1-OPO(
Publikováno v:
Israel Journal of Chemistry. 40:271-277
Glycosylations using glucosyl bromides and various promoters (Et4NBr, HgBr2, or AgOTf) were investigated, competitively and kinetically. The reactions were found to be dependent in both glucosyl bromide and nucleophilic concentration, indicating a SN
Publikováno v:
Journal of the American Chemical Society. 122:11067-11072
Total synthesis of the core heptasaccharyl myo-inositol, Galp(α1−6)Galp(α1−3)Galf(β1−3)[Glcp(α1-PO4-6)Manp](α1−3)Manp(α1−4)GlcNp(α1−6)Ins-1-PO4, and the corresponding hexasaccharyl myo-inositol, Galp(α1−6)Galp(α1−3)Galf(β1
Publikováno v:
Tetrahedron. 56:3969-3975
Synthesis of 1 and 2a is described using a block synthetic strategy. Compound 4 was used as precursor for the two mannose derivatives which, coupled together, forms the dimannoside building block. Thioglycoside 7 was coupled to 8 yielding inositol ph
Publikováno v:
Tetrahedron Letters. 40:3049-3052
A new way of constructing anomeric glycosyl phosphodiester linkages has been explored. Non-anomeric monosaccharide hydrogen phosphonate monoesters (5 and 9) have been used as acceptors in couplings using various benzylated galactosyl donors (trichlor
Publikováno v:
Journal of Carbohydrate Chemistry. 18:31-40
Intermediate oxocarbenium ions or other intermediates produced during acid catalyzed anomerization of some methyl glycosides were trapped by reduction with 4-methylmorpholine borane. The glycosylium ion intermediate formed on anomerization of methyl
Publikováno v:
Tetrahedron. 53:17727-17734
Synthesis of 6-O-(2-amino-2-deoxy-α-D-glucopyranosyl)-D-myo-inositol 1-phosphate, an inner core structure found in various glycosylphosphatidylinositols, and the corresponding 1,2-cyclic phosphate, proposed as part of an insulin second messenger gly