Výsledky vyhledávání - "P. J. C. Fierens"

Étude cinétique des réactions de solvolyse VI. Solvolyses du chlorure de benzyle

Autor: L. Wilputte‐Steinert, P. J. C. Fierens

Publikováno v: Bulletin des Sociétés Chimiques Belges. 65:719-735

The Arrhenius parameters of several solvolysis of benzyl chloride have been measured. As expected, the experimental data do not verify the SN1 Winstein-Grunwald linear relationship. The deviations are expounded on the basis of a new concept “nucleo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::315b58d2aed7e0b9673c4033bc4df6d2
https://doi.org/10.1002/bscb.19560650711

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Effet stérique et représentation plane

Autor: P. J. C. Fierens

Publikováno v: Bulletin des Sociétés Chimiques Belges. 59:649-659

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a04fe462ec01b2522f9ca5de1042ef38
https://doi.org/10.1002/bscb.19500590908

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Hybridation et réactivité. VII. Hydrolyse alcaline de l’acrylate et du propiolate d’iso-propyle

Autor: A. Vermeylen, P. J. C. Fierens

Publikováno v: Périodiques Scientifiques en Édition Électronique.

This paper describes the kinetic study of the alcaline hydrolysis of isopropyl/acrylate and propiolate. The results are expounded on the basis of a previously published interpretation (P. J. C. Fierens, J. Jaminet et P. Kruys. Bull. Soc. China. Beige

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ebc3cac6631b15d07b0417149bfa5120
https://www.persee.fr/doc/barb_0001-4141_1957_num_43_1_68656

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Études cinétiques en série alicyclique. VI. Échange SN2, irréversible, entre les ions iodure et l'α-Chlorocyclohexanone

Autor: P. J. C. Fierens

Publikováno v: Périodiques Scientifiques en Édition Électronique.

The action of potassium iodide on α-chlorocyclopentanone, α-chlorocyclohexanone and 3-chloroheptanone-4, has been studied kinetically. The results are shown to be explainable, on the basis of Winstein's mechanism, by means of an internal steric eff

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::59586149b3d944dcec5ef2949275a205
https://www.persee.fr/doc/barb_0001-4141_1956_num_42_1_68495

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