Zobrazeno 1 - 10
of 21
pro vyhledávání: '"P. D. Kleiber"'
Autor:
W.-Y. Lu, P. D. Kleiber
Publikováno v:
The Journal of Chemical Physics. 114:10288-10293
We have investigated the photodissociation spectroscopy of the Mg+–acetaldehyde bimolecular complex over the spectral range 220–400 nm. We find evidence for four distinct absorption bands in the near ultraviolet that correlate with Mg+-based and
Publikováno v:
The Journal of Chemical Physics. 112:6583-6589
We have studied Ca+(C2H4) by photodissociation spectroscopy in a reflectron time-of-flight mass spectrometer over the spectral range 440–790 nm. Ca+ is the only photofragment observed. We find four absorption bands of the complex and assign them to
Publikováno v:
The Journal of Chemical Physics. 108:5723-5727
We report scattering state spectroscopic studies of the chemical quenching dynamics of Mg*(3p(1P)) by CH4. We have measured the final-state resolved action spectra for the MgH(v=1,N) reactive product channels, following excitation of the Mg*(3p)–CH
Publikováno v:
The Journal of Chemical Physics. 108:2285-2296
The weakly bound ion–molecule complex MgC2H4+ has been studied by photodissociation spectroscopy in a reflectron time-of-flight mass spectrometer over the spectral range 218–510 nm. Mg+ is the major photofragment throughout this range, although f
Publikováno v:
The Journal of Chemical Physics. 106:3884-3890
We report on studies of the structure and dissociation of CaCH4+ and its isotopomer CaCD4+, using photodissociation spectroscopy. Molecular absorption bands are observed to the red of the Ca+ (4p 2P←4s 2S) resonance transition. The photodissociatio
Publikováno v:
The Journal of Chemical Physics. 104:6452-6459
The photodissociation spectroscopy of MgCH+4 has been studied in a reflectron time‐of‐flight mass spectrometer. MgCH+4 molecular absorption bands are observed to the red of the Mg+(3 2PJ←3 2S1/2) atomic ion resonance lines. The photofragmentati
Autor:
P. D. Kleiber, T. H. Wong
Publikováno v:
The Journal of Chemical Physics. 102:6476-6480
We have measured the final state resolved far‐wing action spectra for the MgCH4 reactive collision system. The results show a dramatic ‘‘Π‐like’’ orbital alignment preference in the reaction channel. The reactive channel action spectra f
Publikováno v:
The Journal of Chemical Physics. 102:5235-5245
We have investigated the photofragmentation spectroscopy of Mg2(CO2)+1,2 in a reflectron time‐of‐flight mass spectrometer. For the linear bimolecular complex Mg2(CO2)+, we have observed three distinct molecular absorption bands, in the red, the g
Autor:
P. D. Kleiber, Stephen R. Leone, Mark J. Dalberth, S. S. Op de Beek, J. P. J. Driessen, Eileen M. Spain
Publikováno v:
Journal of Chemical Physics, 102(24), 9532-9536. American Chemical Society
The initial state alignment effect vs relative velocity is measured for a state-to-state Ca Rydberg collisional energy transfer process. The stimulated emission detection method is used to determine the alignment effect for the n,1-changing transitio
Publikováno v:
Annual Review of Physical Chemistry. 44:13-35
Traditional bound-state molecular spectroscopy has long served as a powerful probe of molecular structure and is increasingly being applied to the study of molecular dynamics. For example, the study of spectroscopic perturbations ( l ) can yield prec