Výsledky vyhledávání - "Owen M. Hicks"

Coordination chemistry of a bulky redox-active cyanomanganese carbonyl ligand: N-bound tetrahedral complexes of 3d metals

Autor: Neil G. Connelly, A. Guy Orpen, Andrew J. Wood, Owen M. Hicks, Gareth R. Lewis

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1637-1643

The sterically hindered redox-active cyanomanganese carbonyl complex trans-[Mn(CN)(CO)(dppm)2] acts as an N-donor ligand towards MCl2 (M = Mn, Co or Ni) to give the cyanide-bridged tetrahedral (at M) complexes [Cl2(thf)M(μ-NC)MnLx] {Lx = (CO)(dppm)2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2b5c45e1bedb7307164cad6838cab233
https://doi.org/10.1039/b001782p

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Triphenylboron adducts of redox-active cyanomanganese ligands †

Autor: Neil G. Connelly, A. Guy Orpen, Owen M. Hicks, Dena Bellamy

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :3185-3190

The reaction of [Mn(CN)(PR3)(NO)(η-C5H4Me)] (R = Ph or OPh) with [AuCl(tht)] (tht = tetrahydrothiophene) in the presence of Na[BPh4] gave [Mn(CNBPh3)(PR3)(NO)(η-C5H4Me)], X-ray studies on which (R = OPh) confirm addition of triphenylboron to the ni

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9d4c13c65c155ea25173ea84c7976f75
https://doi.org/10.1039/a902478f

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Novel N-bound thallium(I) complexes of redox-active cyanomanganese carbonyl ligands: cyanide as a μ3-κC∶κN∶κN triply bridging ligand

Autor: Gareth R. Lewis, A. Guy Orpen, M. Teresa Moreno, Neil G. Connelly, Owen M. Hicks

Publikováno v: Journal of the Chemical Society, Dalton Transactions. :1913-1918

The cyanomanganese carbonyls trans-[Mn(CN)(CO)(dppm)2], and cis- and trans-[Mn(CN)(CO)2{P(OR)3}(dppm)] (R = Ph or Et, dppm = Ph2PCH2PPh2) react with TlPF6 to give [(thf)2Tl(µ-NC)Mn(CO)(dppm)2][PF6] 1, [{Tl(µ-NC)MnLx}2][PF6]2 [Lx = cis-(CO)2{P(OR)3}

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9c45ec9120596993a80086398a67d36a
https://doi.org/10.1039/a800765i

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