Zobrazeno 1 - 10
of 59
pro vyhledávání: '"Otto Isler"'
Autor:
Heinrich Kläui, Otto Isler
Publikováno v:
Chemie in unserer Zeit. 15:1-9
Autor:
Otto Isler
Publikováno v:
Pure and Applied Chemistry. 51:447-462
A review is given of the development of the industrial manufacture of carotenoids and vitamin A by isolation and by synthesis. Special emphasis is placed on the use of carotenoids as a preferred class of colouring matters for food and feed.
Publikováno v:
Helvetica Chimica Acta. 40:2354-2368
The influence of nearly all known physiological isoprene-like carboxylic acids with 5 and 6 carbon atoms on the incorporation of [1-14C]-acetate into substances precipitated by digitonine was investigated by means of liver homogenates in buffers with
Publikováno v:
Helvetica Chimica Acta. 44:994-999
The total synthesis of 7′,8′-dihydro-γ-carotene (β-zeacarotene) has been accomplished by a WITTIG reaction of 15,15′-dehydro-apo-12′-carotenal(C35) with farnesyltriphenyl-phosphonium bromide.
Publikováno v:
Helvetica Chimica Acta. 46:650-671
(2R, 4′R, 8′R)- and (2S, 4′R, 8′R)-α-tocopherol have been synthesized by WITTIG reaction of the two enantiomeric S-(+)- and R-(−)-6-acetoxy-Z-formyl-2,5,7, 8-tetramethyl-chromans (I) with (3R, 7R)-hexahydrofarnesyl-triphenylphosphonium bro
Publikováno v:
Helvetica Chimica Acta. 45:528-541
Four crystalline vitamin A2 isomers, i.e. all-trans, 13-cis, 9-cis, and 9,13-di-cis, as well as the corresponding acids and aldehydes, have been prepared from cis- and trans-dehydro-β-ionylideneacetaldehyde.
Publikováno v:
Helvetica Chimica Acta. 49:2582-2589
Phylloquinone, menaquinone-4, ubiquinone-9 and hexahydroplastoquinone-4, i.e. compounds with isoprenoid side-chains which differ by their length and degrees of unsaturation, are degraded in the rat in the same way as tocopherols. After oxidative shor
Autor:
Hans Mayer, L. M. Jackman, M. Kofler, P. Schudel, Rudolf Ruegg, Otto Isler, Gottlieb Ryser, C. von Planta, U. Gloor
Publikováno v:
Helvetica Chimica Acta. 48:1332-1349
The synthesis of trans- and cis-(7′ R,11′ R)-phylloquinone, trans- and cis-menaquinone-2, trans- and cis-(7 R,11 R)-phytol, and related compounds is described. Natural phylloquinone, isolated from alfalfa, is shown to possess the 2′,3′ -trans
Publikováno v:
Helvetica Chimica Acta. 47:221-229
The absolute configuration of natural phylloquinone (vitamin K,) (I) isolated from alfalfa has been determined. The 7′R and 11′R configurations have been derived from the optical rotatory dispersion curves of (6R, lOR)-6,10,14-trimethyl pentadeca
Publikováno v:
Helvetica Chimica Acta. 46:963-982