Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Osamu TOMIOKA"'
Autor:
Osamu Tomioka, Yoshihiro Meguro, Tomoki Imai, Mikio Nakashima, Le Thi Kim Dung, Kuniaki Takahashi
Publikováno v:
Analytical Sciences. 22:1425-1430
The supercritical fluid extraction (SFE) method using CO(2) as a medium with an extractant of HNO(3)-tri-n-butyl phosphate (TBP) complex was applied to extract uranium from several uranyl phosphate compounds and simulated uranium ores. An extraction
Publikováno v:
Journal of Nuclear Science and Technology. 43:98-102
Autor:
Zenko Yoshida, Osamu Tomioka, Yoshihiro Meguro, Shuichi Iso, Youichi Enokida, Ichiro Yamamoto
Publikováno v:
The Journal of Supercritical Fluids. 31:141-147
A new method referred to as supercritical CO 2 fluid leaching (SFL), which is based on selective dissolution of uranium oxides with the supercritical CO 2 fluid containing the HNO 3 –tri- n -butyl phosphate (TBP) complex, has been developed for the
Publikováno v:
Industrial & Engineering Chemistry Research. 42:5037-5041
Tri-n-butyl phosphate (TBP) reacts with nitric acid to form a hydrogen-bonded complex TBP(HNO3)x(H2O)y that is highly soluble in supercritical fluid carbon dioxide (SF-CO2). The value of x can be up to 2.5, whereas the value of y varies between 0.4 a
Publikováno v:
Separation Science and Technology. 37:1153-1162
A method for the direct extraction of a metal utilizing supercritical CO2 containing tri-n-butylphosphate (TBP)–HNO3 (TBP), which is the TBP solution of TBP–HNO3 complex, has been developed for the recovery of Nd from its oxide. This method was a
Publikováno v:
Journal of Nuclear Science and Technology. 38:1097-1102
Dissolution behavior of U3O8 and UO2 using supercritical CO2 medium containing HNO3-TBP complex as a reactant was studied. The dissolution rate of the oxides increased with increasing the HNO3/TBP ratio of the HNO3-TBP complex and the concentration o
Publikováno v:
Journal of Nuclear Science and Technology. 38:1097-1102
Publikováno v:
Progress in Nuclear Energy. 37:417-422
Studied was an application of supercritical fluid extraction (SFE) to cleaning of the materials contaminated with metal oxides. By using supercritical CO2 including chemical complexes of tri-n-buthylphosphate (TBP) and HNO3, lanthanide was recovered
Publikováno v:
ASME 2011 14th International Conference on Environmental Remediation and Radioactive Waste Management, Parts A and B.
A method, in which incinerated ash is solidified with a cement material, has been developed to dispose radioactive incinerated ash waste. In order to bury the solidified product, it is required that elution of hazardous heavy metals included in the a
Publikováno v:
ASME 2010 13th International Conference on Environmental Remediation and Radioactive Waste Management, Volume 1.
To develop a metal separation method using supercritical CO2 (scCO2 ) solvent for the decontamination process of radioactive wastes, the reverse micelle formation in scCO2 was investigated. Dodecyltrimethylammonium bromide (DTAB) as a surfactant to f