Zobrazeno 1 - 2
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pro vyhledávání: '"Onyinye Osisioma"'
Autor:
Onyinye Osisioma, Leanna J. Patton, Rajkumar Merugu, Dmitrii Govorov, Margaret A. Milbrandt, Cassandra Jarus, William L. Karney, Anna D. Gudmundsdottir
Publikováno v:
Photochemistry and photobiologyREFERENCES.
Triplet arylnitrenes may provide direct access to aryl azo-dimers, which have broad commercial applicability. Herein, the photolysis of p-azidostilbene (1) in argon-saturated methanol yielded stilbene azo-dimer (2) through the dimerization of triplet
Publikováno v:
Journal of Molecular Structure. 1172:94-101
Irradiation of 2-azidovinylbenzene (1) in a cryogenic argon matrix with a 254 nm bandpass filter results in 2-phenyl-2H-azirine (2) as the major product, some ketenimine 5, and a small amount of cis-1, whereas irradiation of vinyl azide 1 with light