Zobrazeno 1 - 10 of 806 pro vyhledávání: '"Olmstead MM"'
1
Mixed valence copper-sulfur clusters of highest nuclearity: A Cu8wheel and a Cu16nanoball
Autor: Maji, RC, Das, PP, Bhandari, A, Mishra, S, Maji, M, Ghiassi, KB, Olmstead, MM, Patra, AK
Publikováno v: Maji, RC; Das, PP; Bhandari, A; Mishra, S; Maji, M; Ghiassi, KB; et al.(2017). Mixed valence copper-sulfur clusters of highest nuclearity: A Cu8wheel and a Cu16nanoball. Chemical Communications, 53(23), 3334-3337. doi: 10.1039/c6cc08301c. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/2dj680z3
© 2016 The Royal Society of Chemistry. Fully spin delocalized mixed valence copper-sulfur clusters, 1 and 2, supported by μ4-sulfido and NSthioldonor ligands are synthesized and characterized. Wheel shaped 1 consists of Cu2S2units. The unprecedente
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2
Tethered bis-pyrrolidine additions to C70: Some unexpected and new regioisomers
Autor: Cerón, MR, Izquierdo, M, Aghabali, A, Vogel, SP, Olmstead, MM, Balch, AL, Echegoyen, L
Publikováno v: Cerón, MR; Izquierdo, M; Aghabali, A; Vogel, SP; Olmstead, MM; Balch, AL; et al.(2016). Tethered bis-pyrrolidine additions to C70: Some unexpected and new regioisomers. Carbon, 105, 394-400. doi: 10.1016/j.carbon.2016.04.044. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/9s5760bf
© 2016 Elsevier Ltd. All rights reserved. Four easily isolable bis-pyrrolidine-C70 regioisomers were synthesized and characterized by spectroscopic techniques. The four [70]fullerene bis-adducts were unambiguously assigned using spectroscopic techni
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3
[U(bipy)4]: A Mistaken Case of U0?
Autor: Fortier, S, Veleta, J, Pialat, A, Le Roy, J, Ghiassi, KB, Olmstead, MM, Metta-Magaña, A, Murugesu, M, Villagrán, D
Publikováno v: Fortier, S; Veleta, J; Pialat, A; Le Roy, J; Ghiassi, KB; Olmstead, MM; et al.(2016). [U(bipy)4]: A Mistaken Case of U0?. Chemistry-A European Journal, 22(6), 1931-1936. doi: 10.1002/chem.201504982. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/7vn6235f
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. After more than 50 years, the synthesis and electronic structure of the first and only reported "U0complex" [U(bipy)4] (1) has been reinvestigated. Additionally, its one-electron reduced product [Na
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4
Synthesis and Isolation of the Titanium–Scandium Endohedral Fullerenes—Sc2TiC@Ih-C80, Sc2TiC@D5h-C80and Sc2TiC2@Ih-C80: Metal Size Tuning of the TiIV/TiIIIRedox Potentials
Autor: Junghans, K, Ghiassi, KB, Samoylova, NA, Deng, Q, Rosenkranz, M, Olmstead, MM, Balch, AL, Popov, AA
Publikováno v: Junghans, K; Ghiassi, KB; Samoylova, NA; Deng, Q; Rosenkranz, M; Olmstead, MM; et al.(2016). Synthesis and Isolation of the Titanium–Scandium Endohedral Fullerenes—Sc2TiC@Ih-C80, Sc2TiC@D5h-C80and Sc2TiC2@Ih-C80: Metal Size Tuning of the TiIV/TiIIIRedox Potentials. Chemistry-A European Journal, 22(37), 13098-13107. doi: 10.1002/chem.201601655. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/9381x42k
© 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. The formation of endohedral metallofullerenes (EMFs) in an electric arc is reported for the mixed-metal Sc–Ti system utilizing methane as a reactive gas. Comparison of these result
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http://www.escholarship.org/uc/item/9381x42k
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5
Isolation of CeLu2N at Ih-C80 through a Non-Chromatographic, Two-Step Chemical Process and Crystallographic Characterization of the Pyramidalized CeLu2N within the Icosahedral Cage
Autor: Stevenson, S, Thompson, HR, Arvola, KD, Ghiassi, KB, Olmstead, MM, Balch, AL
Publikováno v: Stevenson, S; Thompson, HR; Arvola, KD; Ghiassi, KB; Olmstead, MM; & Balch, AL. (2015). Isolation of CeLu2N at Ih-C80 through a Non-Chromatographic, Two-Step Chemical Process and Crystallographic Characterization of the Pyramidalized CeLu2N within the Icosahedral Cage. Chemistry-A European Journal. doi: 10.1002/chem.201500915. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/7n26382g
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. By combining two chemical methods of purification, 4mg of purified CeLu2N at C80 was readily isolated from 500mg of carbon soot extract without the use of recycling HPLC, a method which has previous
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6
Bis[3,3-dimethyl-2-(2-oxoethyl-idene)indolinyl-κ 2 N,O]palladium(II)
Autor: Khaledi, H, Olmstead, MM, Mohd Ali, H
Publikováno v: Khaledi, H; Olmstead, MM; & Mohd Ali, H. (2011). Bis[3,3-dimethyl-2-(2-oxoethyl-idene)indolinyl-κ 2 N,O]palladium(II). Acta Crystallographica Section E: Structure Reports Online, 67(7), M929-U1020. doi: 10.1107/S1600536811022069. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/0z69m6mf
The asymmetric unit of the title compound, [Pd(C 12H 12NO) 2], consists of three crystallographically independent half-mol-ecules. Each Pd II atom lies on a center of inversion and is four-coordinated by two monoanionic forms of the amino-acryl-aldeh
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7
Poly[[piperazine-1,4-dium [diaqua-tetrakis(μ-sulfanediyldiacetato) dicerate(III)]] trihydrate]
Autor: Ghadermazi, M, Olmstead, MM, Rostami, S, Attar Gharamaleki, J
Publikováno v: Ghadermazi, M; Olmstead, MM; Rostami, S; & Attar Gharamaleki, J. (2011). Poly[[piperazine-1,4-dium [diaqua-tetrakis(μ-sulfanediyldiacetato) dicerate(III)]] trihydrate]. Acta Crystallographica Section E: Structure Reports Online, 67(3), M291-U135. doi: 10.1107/S1600536811002923. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/38t9z4t0
The title compound, (C4H12N2)[Ce 2(C4H4O4S)4(H 2O)2]·3H2O, features a polymeric anion with a centrosymmetric Ce2O2 core and a Ce⋯Ce distance of 4.3625 (4) Å. The anions form ribbons {[Ce2(C 4H4O4S)4(H2O) 2]2-}n extending along [100]. The doubly p
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http://www.escholarship.org/uc/item/38t9z4t0
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8
Incorporation of μ3-CO3 into an Mn III/MnIV Mn12 cluster: {[(cyclam)Mn IV(μ-O)2MnIII(H2O)(μ-OH)] 6(μ3-CO3)2}Cl8· 24H2O
Autor: Levaton, BB, Olmstead, MM
Publikováno v: Levaton, BB; & Olmstead, MM. (2010). Incorporation of μ3-CO3 into an Mn III/MnIV Mn12 cluster: {[(cyclam)Mn IV(μ-O)2MnIII(H2O)(μ-OH)] 6(μ3-CO3)2}Cl8· 24H2O. Acta Crystallographica Section E: Structure Reports Online, 66(10), M1226-MU564. doi: 10.1107/S1600536810034999. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/20z6x3zh
The centrosymmetric title cluster, hexaaquadi-3-carbonatohexacyclamhexa- μ2-hydroxido-dodeca-μ2-oxido-hexamanganese(IV) hexa-manganese(III) octa-chloride tetra-cosa-hydrate, [Mn12(CO 3)2O12(OH)6(C10H 24N4)6(H2O)6]Cl 8·24H2O, has two μ3-CO3 groups
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9
Flux growth and structure of two compounds with the EuIn2P2structure type, AIn2P2(A = Ca and Sr), and a new structure type, BaIn2P2
Autor: Rauscher, JF, Condron, CL, Beault, T, Kauzlarich, SM, Jensen, N, Klavins, P, Maquilon, S, Fisk, Z, Olmstead, MM
Publikováno v: Rauscher, JF; Condron, CL; Beault, T; Kauzlarich, SM; Jensen, N; Klavins, P; et al.(2009). Flux growth and structure of two compounds with the EuIn2P2structure type, AIn2P2(A = Ca and Sr), and a new structure type, BaIn2P2. Acta Crystallographica Section C: Crystal Structure Communications, 65(10), i69-i73. doi: 10.1107/S0108270109035987. UC Irvine: Retrieved from: http://www.escholarship.org/uc/item/6sb0r7w1
Single crystals of the new Zintl phases AIn2P2[A = Ca (calcium indium phosphide), Sr (strontium indium phosphide) and Ba (barium indium phosphide)] have been synthesized from a reactive indium flux. CaIn2P2and SrIn2P2are isostructural with EuIn2P2and
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10
Poly[[tri - Cyanido-cyanido(1,4,10,13-tetra-oxa-7,16-diaza-cyclo-octa-deca- ne)barium(II)platinum(II)] hemihydrate]
Autor: Olmstead, MM, Beavers, CM, Paw U, L
Publikováno v: Olmstead, MM; Beavers, CM; & Paw U, L. (2009). Poly[[tri-Cyanido-cyanido(1,4,10,13-tetra-oxa-7,16-diaza-cyclo-octa-deca-ne)barium(II)platinum(II)] hemihydrate]. Acta Crystallographica Section E: Structure Reports Online, 65(4), M408-U596. doi: 10.1107/S1600536809008915. UC Davis: Retrieved from: http://www.escholarship.org/uc/item/2zw2h6pc
The title compound, {[BaPt(CN)4(C12H 26N2O4)]·0.5H2O} n , is a two-dimensional coordination polymer in which the sheets are oriented approximately parallel to the ( 01) set of crystal planes. In the crystal structure, disordered water mol-ecules (ha
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