A self-crosslinking monomer, α-pinene methacrylate: understanding and exploiting hydrogen abstraction

Autor: Olivia R. Monaghan, Stephen T. Skowron, Jonathan C. Moore, María Pin-Nó, Kristoffer Kortsen, Rachel L. Atkinson, Eduards Krumins, Joachim C. Lentz, Fabricio Machado, Zeynep Onat, Adam Brookfield, David Collison, Andrei N. Khlobystov, Davide De Focatiis, Derek J. Irvine, Vincenzo Taresco, Robert A. Stockman, Steven M. Howdle

Publikováno v: Monaghan, O R, Skowron, S T, Pin-Nó, M, Kortsen, K, Krumins, E, Lentz, J C, Machado, F, Onat, Z, Khlobystov, A N, Focatiis, D D, Irvine, D J, Taresco, V, Stockman, R A & Howdle, S M 2022, ' A self-crosslinking monomer, α-pinene methacrylate: understanding and exploiting hydrogen abstraction ', Polymer Chemistry, vol. 13, no. 39, pp. 5557-5567 . https://doi.org/10.1039/d2py00878e

Crosslinking is a valuable route to creating new polymeric materials and normally involves introduction of a cross linker or some form of secondary processing. Here we report the discovery and analysis of a self-crosslinking sustainable terpene deriv

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8d7cc45d7e8be3cf58e9a7a83ae475e3
https://doi.org/10.1039/d2py00878e

Controlling the melting transition of semi-crystalline self-assembled block copolymer aggregates

Autor: Olivia R. Monaghan, Simon J. Holder, Phh Paul Bomans, Nico A. J. M. Sommerdijk

Publikováno v: Polymer Chemistry, 8(35), 5303-5316. Royal Society of Chemistry

Bicontinuous nanospheres and multi-lamellar micelles were self-assembled from poly[ethylene oxide]-block-(poly[octadecyl methacrylate]-random-poly[docosyl methacrylate]), (PEO-b-[PODMA-co-PDSMA]) where PEO is the hydrophilic block (25 wt%) and PODMA/

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::738563c105ec37177dcc1450ea50e470
https://research.tue.nl/en/publications/abf0b822-10ec-4457-98ed-d72d63c9f521

Progress in the synthesis of sustainable polymers from terpenes and terpenoids

Autor: Thomas E. Storr, Robert A. Stockman, Olivia R. Monaghan, Megan R. Thomsett, Steven M. Howdle

The imminent depletion of resources derived from fossil fuels is a major concern for today’s society. 300 Mt of polymers are used every year in the form of plastics, most commonly derived from fossil fuels, hence the necessity to find new materials

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a2602b49ce7b4251acf4a3477576e92
https://ueaeprints.uea.ac.uk/id/eprint/62944/

Controlling Internal Pore Sizes in Bicontinuous Polymeric Nanospheres

Autor: Simon J. Holder, Fabio Nudelman, Beulah E. McKenzie, Maarten J. M. Wirix, Joël F. de Visser, Nico A. J. M. Sommerdijk, Heiner Friedrich, Paul H. H. Bomans, Olivia R. Monaghan

Publikováno v: Angewandte Chemie-International Edition, 54(8), 2457-2461. Wiley
Angewandte Chemie (International Ed. in English)

Complex polymeric nanospheres were formed in water from comb-like amphiphilic block copolymers. Their internal morphology was determined by three-dimensional cryo-electron tomographic analysis. Varying the polymer molecular weight (MW) and the hydrop

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::901e906e720df143da7247dbce95dc48
https://kar.kent.ac.uk/50605/1/McKenzie_et_al-2015-Angewandte_Chemie_International_Edition(1).pdf

Back Cover: Controlling Internal Pore Sizes in Bicontinuous Polymeric Nanospheres (Angew. Chem. Int. Ed. 8/2015)

Autor: Maarten J. M. Wirix, Nico A. J. M. Sommerdijk, Olivia R. Monaghan, Joël F. de Visser, Simon J. Holder, Fabio Nudelman, Heiner Friedrich, Beulah E. McKenzie, Paul H. H. Bomans

Publikováno v: Angewandte Chemie International Edition. 54:2562-2562

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::acd7536d7c09f32ec6b2384fd5a0f958
https://doi.org/10.1002/anie.201500264