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Autor:
Matthew A. Cranswick, Kristie R. Ruddick, Dennis L. Lichtenberger, Wolfdieter A. Schenk, Olivia Oorhles-Steele, Nadine E. Gruhn, Nicolai Burzlaff
Publikováno v:
Inorganica Chimica Acta. 361:1122-1133
The metal–sulfur bonding present in the transition metal–thiolate complexes CpFe(CO)2SCH3, CpFe(CO)2StBu, CpRe(NO)(PiPr3)SCH3, and CpRe(NO)(PPh3)SCH3 (Cp = η5-C5H5) is investigated via gas-phase valence photoelectron spectroscopy. For all four c