Zobrazeno 1 - 10
of 31
pro vyhledávání: '"Oleksandr Kysliak"'
Autor:
Oleksandr Kysliak, Simon H. F. Schreiner, Niklas Grabicki, Phil Liebing, Florian Weigend, Oliver Dumele, Robert Kretschmer
Publikováno v:
Angewandte Chemie. 134
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8c646730b72a92fad6634a15e2172367
https://doi.org/10.1002/ange.202206963
https://doi.org/10.1002/ange.202206963
Autor:
Oleksandr Kysliak, Simon H. F. Schreiner, Niklas Grabicki, Phil Liebing, Florian Weigend, Oliver Dumele, Robert Kretschmer
Publikováno v:
Angewandte Chemie (International ed. in English). 61(31)
Many chemicals known today are partially or fully aromatic, since a ring framework experiences additional stabilization through the delocalization of π‐electrons. While aromatic rings with equal numbers of π‐electrons and ring atoms such as ben
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7d5dca20cf7bb173d079cd268e7effff
https://pubmed.ncbi.nlm.nih.gov/35593009
https://pubmed.ncbi.nlm.nih.gov/35593009
Publikováno v:
Journal of the American Chemical Society. 143:142-148
Inspired by natural metalloenzymes that efficiently catalyze a variety of transformations, chemists have developed large numbers of dinuclear transition-metal complexes with extraordinary properties and reactivity patterns. For main-group element com
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7ecd73d7343166e9390efbf6e77c79d
https://doi.org/10.1021/jacs.0c12166
https://doi.org/10.1021/jacs.0c12166
Publikováno v:
Dalton Transactions. 49:6377-6383
Salt metathesis, i.e. the reaction of sodium β-diketiminate with (AlCp*)4 and GaCp*, respectively, is a valuable pathway to access the respective aluminium(i) and gallium(i) β-diketiminates I and II. The protocol gives better yields compared to the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::971c0a5d907d416df02c98460d64ab28
https://doi.org/10.1039/d0dt01342k
https://doi.org/10.1039/d0dt01342k
Publikováno v:
Chemical communications (Cambridge, England). 56(57)
The reaction of (Cp*Al)4 with a series of fluoro(hetero)arenes has been investigated and C–F bond activation was observed with perfluorotoluene, pentafluoropyridine as well as 1,2,3,4-tetrafluoro-, pentafluoro- and hexafluorobenzene. The reaction m
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::be43a59c64e32aa4fba102be909f773e
https://pubmed.ncbi.nlm.nih.gov/32037419
https://pubmed.ncbi.nlm.nih.gov/32037419
Publikováno v:
Inorganic Chemistry. 57:12603-12609
The reaction of [ZnGe18(Hyp)6] (Hyp = Si(SiMe3)3) with Pt(PPh3)4 gives the neutral polynuclear complex of Ge9(Hyp)3 units [HypZn–Ge9(Hyp)3–Pt–Ge9(Hyp)3–ZnHyp], 1. Within 1, the central Pt atom is b...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::210b9c085ed1d5c1645e1e206d9ae94a
https://doi.org/10.1021/acs.inorgchem.8b01757
https://doi.org/10.1021/acs.inorgchem.8b01757
Autor:
Oleksandr Kysliak, Andreas Schnepf
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 645:335-339
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d8f678c9758b128c7e570908978c5539
https://doi.org/10.1002/zaac.201800296
https://doi.org/10.1002/zaac.201800296
Publikováno v:
Inorganic Chemistry. 56:9693-9697
The reaction of [(Hyp)2Ge9]2– (Hyp = Si(SiMe3)3) with ClSiMe2-C6H4-SiMe2Cl gives [K(THF)][(Hyp)2Ge9-SiMe2-C6H4-SiMe2-Ge9(Hyp)2K] K1 in 45% yield in the form of orange-red crystals. 1 is thereby the first compound where two Ge9(Hyp)2 clusters are bo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b6b25f64b6ec6b222197a1e0e1784690
https://doi.org/10.1021/acs.inorgchem.7b01186
https://doi.org/10.1021/acs.inorgchem.7b01186
Publikováno v:
European Journal of Inorganic Chemistry. 2017:805-810
The synthesis and characterization of the metalloid germanium clusters {Ge9[Si(SiMe3)2(SiPh3)]2}2– (1), {Ge9[Si(SiMe3)3][Si(SiMe3)2(SiPh3)]2}– (2), {Ge9[Si(SiMe3)2(SiiPr3)]3}– (3), and [Ge9(SiHtBu2)3]– (4), which were obtained by the reaction
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c70ad4b3ac489ffbe3d16e2904e4dff4
https://doi.org/10.1002/ejic.201601134
https://doi.org/10.1002/ejic.201601134
Publikováno v:
Chemistry - A European Journal. 22:18787-18793
Recently the metalloid cluster compound [Ge9 Hyp3 ]- (1; Hyp=Si(SiMe3 )3 ) was oxidatively coupled by an iron(II) salt to give the largest metalloid Group 14 cluster [Ge18 Hyp6 ]. Such redox chemistry is also possible with different transition metal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f1cdb06be6e074d042d5cd9a13df1d1a
https://doi.org/10.1002/chem.201603441
https://doi.org/10.1002/chem.201603441