Postsynthetic Selective Ligand Cleavage by Solid–Gas Phase Ozonolysis Fuses Micropores into Mesopores in Metal–Organic Frameworks

Autor: Daniel Maspoch, Jorge Albalad, Heng Xu, Vincent Guillerm, Inhar Imaz

Publikováno v: Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona
Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2018, 140 (44), pp.15022-15030. ⟨10.1021/jacs.8b09682⟩
Digital.CSIC. Repositorio Institucional del CSIC
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Herein we report a novel, ozone-based method for postsynthetic generation of mesoporosity in metal–organic frameworks (MOFs). By carefully selecting mixed-ligand Zr-fcu-MOFs based on organic ligand pairs in which one ligand has ozone-cleavable olef

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afe6bd1599417a89d2ca589189822e15
https://doi.org/10.1021/jacs.8b09682