Mechanism of the Molybdenum-Mediated Cadogan Reaction

Autor: Marta Castiñeira Reis, Marta Marín-Luna, Carlos Silva López, Olalla Nieto Faza

Publikováno v: ACS Omega, Vol 3, Iss 6, Pp 7019-7026 (2018)

Externí odkaz: https://doaj.org/article/d42823b586c64bbd9ff14cacd2010ef4

Three cycles in the dioxomolybdenum-catalyzed reduction of nitrobenzenes to anilines with pinacol. A computational study towards the valorization of biomass subproducts

Autor: Sofia Kiriakidi, Carlos Silva López, Olalla Nieto Faza

In this work, we use density functional theory to unravel the mechanism of the nitrobenzene to aniline reduction, catalyzed by dioxomolybdenum (VI) dichloride. The use of pinacol as an oxoaccepting reagent and the production of only acetone and water

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::056bbb818a811972b39d2624f105bee0
https://doi.org/10.26434/chemrxiv-2023-cgtdn

Au(III) Catalyzes the Cross-Coupling Between Activated Methylenes and Alkene Derivatives

Autor: Olalla Nieto Faza, Marta Castiñeira Reis, Nenad Janković, Carlos Silva López, Marta Marin-Luna

Publikováno v: Journal of Catalysis, 392, 159-164. ACADEMIC PRESS INC ELSEVIER SCIENCE

In the last decade substantial efforts were devoted towards the exploitation of the Au(I) as a promising tool to promote C[sbnd]C bond formation reactions via the activation of unsaturations. Among these efforts, Au(I)/Au(III) cross couplings mediate

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0d95fc1ddf3f931b84524be0b32defb
https://doi.org/10.1016/j.jcat.2020.09.030

Acetate-catalyzed hydroboration of CO2 for the selective formation of methanol-equivalent products

Autor: Béatrice Jacques, João Henrique Zimnoch dos Santos, Carlos Silva López, Yuri C. A. Sokolovicz, David Specklin, Henri Stephan Schrekker, Olalla Nieto Faza, Samuel Dagorne

Publikováno v: Catalysis Science & Technology
Catalysis Science & Technology, Royal Society of Chemistry, 2020, 10 (8), pp.2407-2414. ⟨10.1039/d0cy00118j⟩

International audience; The present study details the use of the acetate anion, an inexpensive and robust anion, as a CO2 hydroboration catalyst for the selective formation, in most cases, of methanol-equivalent borane products. Thus, upon heating (9

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b1368bdc63a70a3d3020d45eb8248e56
https://doi.org/10.1039/d0cy00118j

On the mechanism of the dyotropic expansion of hydrindanes into decalins

Autor: Hugo Santalla, Olalla Nieto Faza, Generosa Gómez, Yagamare Fall, Carlos Silva López

Publikováno v: Organicbiomolecular chemistry. 20(5)

A combined computational/experimental approach has revealed key mechanistic aspects in a recently reported dyotropic expansion of hydrindanes into decalins. While computer simulations had already anticipated the need for acid catalysis for making thi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::640c14ccc7dfaee5f3336b73901035af
https://pubmed.ncbi.nlm.nih.gov/35029264