Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Okba Saied"'
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 61:o2563-o2566
The title compound, C32H36O8Si, crystallizes from CH2Cl2 by slow evaporation to produce a close-packed structure. In this structure, the molecules have crystallographic \overline{4} symmetry and no guest molecules are included. In contrast, crystal
Publikováno v:
Canadian Journal of Chemistry. 76:490-497
Carbonyl oxygen atoms have two formal lone pairs of electrons. In principle, both can be used simultaneously to form complexes with two or more Lewis acids. This multiple coordination promises to have a variety of interesting consequences; unfortunat
Publikováno v:
Organometallics. 17:1128-1133
Treatment of 2,2‘-(1,3-butadiyne-1,4-diyl)bis[6-(1,1-dimethylethyl)-4-methylphenol] (1) with 2 equiv of Al(i-Bu)3 converts the two hydroxyl groups into OAl(i-Bu)2 groups, thereby transforming diphenol 1 into the corresponding bis(di-i-butylaluminum
Publikováno v:
Canadian Journal of Chemistry. 76:490-497
Publikováno v:
Organometallics. 15:2345-2349
Treatment of 2,2‘-(1,2-ethynediyl)bis[6-(1,1-dimethylethyl)-4-methylphenol] (2) with 2 equiv of Al(i-Bu)3 converts the hydroxyl groups into potentially Lewis acidic OAl(i-Bu)2 groups with a convergent orientation. Their intramolecular interaction p
Publikováno v:
Inorganic chemistry. 37(11)
Treatment of 2,7-bis(1,1-dimethylethyl)fluorene-1,8-diol (3) with 2 equiv of TiCl(4) converts the two OH groups into OTiCl(3) groups and thereby yields bis(trichlorotitanium phenoxide) 7, a structurally well-defined reagent that holds two sites of st
Submaximal Interpenetration and Bicontinuous Three-Dimensional Channels in Porous Molecular Networks
Publikováno v:
Journal of the American Chemical Society. 127:10008-10009
Crystallization of tetrakis(3,5-dihydroxyphenyl)silane (1) from various solvents produces structures built from interpenetrated hydrogen-bonded diamondoid networks. Crystals grown from hexane/methyl propiolate show 5-fold interpenetration, with no vo
Publikováno v:
Journal of the American Chemical Society. 125:14956-14957
A strategy for making molecular networks that are porous and deformable is revealed by the behavior of compound 1, in which groups that form hydrogen bonds are attached to a nominally tetrahedral Si core. Compound 1 crystallizes from various carboxyl
Publikováno v:
The Journal of Organic Chemistry. 63:3756-3757