Comparison of dimensionality reduction techniques for the visualisation of chemical space in organometallic catalysis

Autor: Mario Villares, Carla M. Saunders, Natalie Fey

Publikováno v: Artificial Intelligence Chemistry, Vol 2, Iss 1, Pp 100055- (2024)

We have used a Ligand Knowledge Base for bidentate P,P-donor ligands of potential interest to homogeneous catalysis to compare three dimensionality reduction techniques, namely Principal Component Analysis (PCA), Uniform Manifold Approximation and Pr

Externí odkaz: https://doaj.org/article/01e7247ef7574b6f99c3b8ce8bd8663a

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Nickel‐Catalyzed Cyanoalkylation of Ketone Derivatives

Autor: Anaïs Coffinet, Vincent Levacher, Isabelle Gillaizeau, Jean‐François Brière, Sylvain Oudeyer

Publikováno v: Advanced Synthesis and Catalysis
Advanced Synthesis and Catalysis, 2023, Advanced Synthesis & Catalysis, 365, pp.156-160. ⟨10.1002/adsc.202201147⟩

International audience; Although the metal-based catalyzed cyanomethylation of aldehydes is well-developed, a similar approach to ketones with acetonitrile derivatives remains a challenge. Thanks to Tolman type complexes, NiIIcomplexes with a pyridin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::366bfbd663255f79b502630c8443f20b
https://doi.org/10.1002/adsc.202201147

Functional polyesters via ring-opening copolymerization of $\alpha$–hydroxy–$\gamma$–butyrolactone and $\epsilon$-caprolactone: La[$N(SiMe_3)_2]_3$ as an efficient coordination-insertion catalyst

Autor: Chloé Pascouau, Anne-Laure Wirotius, Stéphane Carlotti, Henri Cramail, Frédéric Peruch

Publikováno v: European Polymer Journal
European Polymer Journal, 2023, 185, pp.111793. ⟨10.1016/j.eurpolymj.2022.111793⟩

International audience; The growing awareness of environmental concerns and the fossil resources depletion have raised the need to develop sustainable and degradable polymers such as aliphatic polyesters. $\gamma$-Lactone-based polyesters are of grea

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::73f91d3033e588c3eacb92051bf427c9
https://hal.science/hal-03975357/document