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pro vyhledávání: '"O. Morawski"'
Akademický článek
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Publikováno v:
The Journal of Organic Chemistry
The tandem process of phenol addition to a cyclic α,β-unsaturated ester followed by intramolecular transesterification and [1,5] sigmatropic rearrangement affords a series of helical coumarins based upon a previously unknown 3-amino-7-hydroxybenzo[
Publikováno v:
Physical Chemistry Chemical Physics. 22:15437-15447
Photophysics of hexaazatrinaphthylene (HATN) in solution and in the solid state is determined by the nπ* character of its lowest excited singlet state and by the ππ* character of the first triplet state. The relaxation of an electronically excited
Akademický článek
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Publikováno v:
Physical Chemistry Chemical Physics. 21:8314-8325
A structurally unique cyclic tris-coumarin possessing three identical coumarin units bridged by amide linkers as well as two linear analogs has been synthesized. There is a remarkable agreement between crystallographic data, 1H NMR and results of cal
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 26(32)
Linking a polarized coumarin unit with an aromatic substituent via an amide bridge results in weak electronic coupling that affects the intramolecular electron-transfer (ET) process. As a result of this, interesting solvent-dependent photophysical pr
Publikováno v:
Physical Chemistry Chemical Physics. 20:14491-14503
The fluorescence intensity of bis-coumarins linked via CONH and COO functionalities are shown to exhibit a strong dependance on solvent polarity. The presence of the intramolecular hydrogen bond between the C[double bond, length as m-dash]O oxygen at
Autor:
Bolesław Kozankiewicz, O. Morawski, Andrzej L. Sobolewski, Pawel Gawrys, Marzena Banasiewicz, Joanna Olas, Sergiu Shova, Kinga Suwińska, Cristina A. Barboza
Publikováno v:
Journal of Molecular Liquids. 343:117532
Four donor–acceptor salicylaldimines with benzoheterocyclic substituents at nitrogen imine were prepared and characterised by means of optical spectroscopy. Their luminescent properties were compared with two isoelectronic carbocyclic analogues. In
Publikováno v:
Chemistry - A European Journal. 23:9174-9184
The synthesis of a weakly coupled, strongly polarized coumarin dimer has been achieved for the first time. The three-step strategy comprises the Skattebøl formylation followed by the Knoevenagel reaction and the formation of a tertiary amide by usin
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 25(67)
Coumarins are classic, strongly polarized fluorophores with multiple applications, and significant efforts have been put into modifying their emission characteristics and elucidating their photophysics. Expecting that π-expansion of these donor-acce