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pro vyhledávání: '"Nuria Brugat"'
Autor:
Cristobal Segura, Josep Duran, Xavier Fontrodona, Jordi Benet-Buchholz, Julio Real, Alfonso Polo, Nuria Brugat
Publikováno v:
Organometallics. 22:3432-3438
The chiral ligand (1R,2S,5R)-1-((diphenylphosphino)methyl)-2-isopropyl-5-methylcyclohexanethiol (4) has been prepared from low-cost commercial (−)-menthone in a three-step enantioselective synthesis. Oxidative addition of 2 equiv of this phosphinot
Synthesis and characterization of a new chiral phosphinothiol ligand and its palladium(II) complexes
Autor:
Josep Duran, Julio Real, J.Francesc Piniella, Alfonso Polo, Angel Alvarez-Larena, Nuria Brugat
Publikováno v:
Tetrahedron: Asymmetry. 13:569-577
The chiral ligand (1-diphenylphosphino-3-benzyloxy)propane-2-thiol 3 has been prepared both in racemic and enantiomerically enriched (92% e.e.) form. Addition of 2 equiv. of ligand 3 to a solution of [Pd(PPh3)4] gave the diastereoisomeric bischelate
Publikováno v:
Inorganic chemistry. 38(21)
The phosphinothiolato complexes [PdCl(dppet)PPh(3)] (3), [Pd(dppet)(2)] (4), and [Pd(2)Cl(2)(dpppt-P,mgr;-S)(2)] (6) (Hdppet = HSC(2)H(4)PPh(2); Hdpppt = HSC(3)H(6)PPh(2)) have been synthesized in good yield by various base-free ligand exchange react