Zobrazeno 1 - 10
of 183
pro vyhledávání: '"Norrish reaction"'
Akademický článek
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Autor:
Fang Rong Chang, Ching-Ying Lee, Yuan-Bin Cheng, Shih-Wei Wang, Jyh-Horng Sheu, Shu-Rong Chen
Publikováno v:
Organic & Biomolecular Chemistry. 18:7892-7898
A phytochemical investigation of Aleurites moluccanus yielded one novel dinor-diterpenoid, aleuritin (1), along with a rare diterpenoid, aleuritone (2). Compound 1 has an unprecedented skeleton with a 6/6/5-fused tricyclic ring system. Compound 2 pos
Akademický článek
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Publikováno v:
Computational and Theoretical Chemistry. 1047:55-66
For the first time within the unified quantum chemical scheme of calculations (method CASSCF – complete active space self-consistent field; basis 6-31+G* with diffusion functions on the atoms N, O) the competition of Norrish and Norrish-like reacti
Publikováno v:
Tetrahedron. 65:9952-9955
Two approaches for the photochemical synthesis of cyclopentene derivatives through the Norrish type II cleavage reaction were described. Asymmetric studies using ionic chiral auxiliaries afforded enantiomeric excesses of up to 98% at the conversion o
Publikováno v:
The Journal of Organic Chemistry. 73:6711-6715
A synthetic approach to the A-B ring system within the fusicoccane family of diterpenes is presented. Key steps in this approach are a diastereoselective Pauson-Khand reaction, a Norrish 1 photofragmentation, a Charette cyclopropanation, and a ring-c
Publikováno v:
The Journal of Organic Chemistry. 72:6786-6791
Reaction of crystals of 2,4,6-triisopropylbenzophenone derivative with the (S)-phenylethylamide group caused diastereospecific Norrish type II photocyclization by UV irradiation to give (R,S)-cyclobutenol as a sole product. In contrast, the solution
Autor:
Cornelia Bohne, Tamara C. S. Pace, Narayanasami Sathyamurthy, Brijesh Kumar Mishra, Jarugu Narasimha Moorthy, Subhas Samanta
Publikováno v:
The Journal of Organic Chemistry. 71:4453-4459
The phenomenon of beta-phenyl quenching has been examined by laser-flash photolysis in a series of alpha- and/or beta-substituted ketones 4-8 with similar excited-state characteristics. It is found that alpha-substitution markedly increases the tripl
Publikováno v:
Journal of the American Chemical Society. 127:13200-13206
A styrene-based water-soluble polymer has been explored for its use as a host for lipophilic substrates in aqueous medium. Unimolecular reactions, namely, photo-Fries rearrangement of naphthyl esters, alpha-cleavage reaction of 1-phenyl-3-p-tolyl-pro
Autor:
Michael J. Kelley, Zhengmao Zhu
Publikováno v:
Polymer. 46:8883-8891
Infrared spectroscopy provides a comprehensive view of chemical and conformational structures of molecules. Spin cast amorphous and semicrystalline PET thin films on silicon substrates were investigated with transmission IR to reveal the effect of de