f-Orbital Mixing in the Octahedral f2 Compounds UX62– [X = F, Br, Cl, I] and PrCl63–

Autor: Wayne W. Lukens, Norman M. Edelstein

Publikováno v: The Journal of Physical Chemistry A. 124:4253-4262

Understanding how interactions between the f orbitals and ligand orbitals in lanthanide and actinide systems affect their physical properties is the central issue in f-element chemistry. A wide variety of approaches including both theoretical and exp

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5dd7ef88a6aa530f2ac6fc184d42b01f
https://doi.org/10.1021/acs.jpca.0c02022

Correction to 'Quantifying the σ and π Interactions between U(V) f Orbitals and Halide, Alkyl, Alkoxide, Amide and Ketimide Ligands'

Autor: Nicola Magnani, Lani A. Seaman, Norman M. Edelstein, Trevor W. Hayton, Skye Fortier, Wayne W. Lukens

Publikováno v: Journal of the American Chemical Society, vol 142, iss 11

Author(s): Lukens, Wayne W; Edelstein, Norman M; Magnani, Nicola; Hayton, Trevor W; Fortier, Skye; Seaman, Lani A | Abstract: While preparing a follow-up manuscript, we found an error in one of the orbital reduction factors used in our crystal field

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https://escholarship.org/uc/item/9f1302t7

Reanalysis of the Aqueous Spectrum of the Neptunyl(V) [NpO2+] Ion

Autor: Norman M. Edelstein

Publikováno v: Edelstein, NM. (2015). Reanalysis of the Aqueous Spectrum of the Neptunyl(V) [NpO2+] Ion. Journal of Physical Chemistry A, 119(45), 11146-11153. doi: 10.1021/acs.jpca.5b08576. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/2fc4283z

© 2015 American Chemical Society. The actinyl ions, consisting of the dioxoactinde(VI) and dioxoactinide(V) ions, are unique in the periodic table. However, very few quantitative studies of the spectra of these ions have been performed. In this pape

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1470f41e9e570093c687b32c6c00167d
https://doi.org/10.1021/acs.jpca.5b08576

Optical Spectra and Crystal-Field Levels of [Cm(H2O)9]3+ Ions with C3h Symmetry in Isotypic Rare-Earth Triflate and Ethyl Sulfate Salts

Autor: Norman M. Edelstein, Clemens Walther, Reinhardt Klenze, Patric Lindqvist-Reis

Publikováno v: The Journal of Physical Chemistry C. 113:449-458

crystal-field levels of the ground state as sharp and narrowly spaced lines. The total ground-state splittings in 1 (8.0 cm -1 ), 2 (6.0 cm -1 ), and 3 (7.5 cm -1 ) are about three to four times larger than those for Cm 3+ in LaCl3 (2.0 cm -1 ), but

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https://doi.org/10.1021/jp808491k

Evolution of Technetium Speciation in Reducing Grout

Autor: Jerome J. Bucher, Norman M. Edelstein, Wayne W. Lukens, David K. Shuh

Publikováno v: Lukens, Wayne W.; Bucher, Jerome J.; Shuh, David K.; & Edelstein, Norman M.(2003). Evolution of technetium speciation in reducing grout. Lawrence Berkeley National Laboratory. Lawrence Berkeley National Laboratory: Lawrence Berkeley National Laboratory. Retrieved from: http://www.escholarship.org/uc/item/1dv1g406

Cementitious waste forms (CWFs) are an important component of the strategy to stabilize nuclear waste resulting from plutonium production by the U. S. Department of Energy. Technetium (99Tc) is an abundant fission product of particular concern in CWF

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::38a655c12fcba03a3e2314313364c972
https://doi.org/10.1021/es050155c