Gold-Catalyzed Access to Isophosphinoline 2-Oxides

Autor: Gabin Mwande-Maguene, Hooriye Boosaliki, Jean-Luc Pirat, Minh Loan Tran Do, Jacques Lebibi, David Virieux, Tahar Ayad, Mina Hariri, Nora Sechet, Karen-Pacelye Mengue Me Ndong, Geraud Chacktas, Fatemeh Darvish, A. R. Burilov

Publikováno v: Journal of Organic Chemistry
Journal of Organic Chemistry, American Chemical Society, 2021, 86 (11), pp.7813-7824. ⟨10.1021/acs.joc.1c00648⟩

Gold(I)-catalyzed reactions of electron-poor alkynes are still a challenging process. A straightforward synthesis of phosphorus-based heterocycles, namely, 2-phenyl 1H-isophosphinoline 2-oxides 1, is reported. The reaction used PPh3AuCl precatalyst i

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