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pro vyhledávání: '"Nooy, A.E.J. de"'
Publikováno v:
ACS Symposium Series, 688, 73-82
Three methods for the selective oxidation of cellulose are described. The classical method consists of consecutive oxidation with sodium periodate, leading to 2,3-dialdehyde cellulose and sodium chlorite, giving 2,3-dicarboxy cellulose. This material
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Publikováno v:
Tetrahedron, 29, 51, 8023-8032
The kinetics of the TEMPO-mediated oxidation of methyl α-D- glucopyranoside to sodium methyl α-D-glucopyranosiduronate were studied. An intermediate was found which was identified as the hydrated aldehyde. This was oxidised in the same manner as th
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Publikováno v:
Carbohydrate Research, 1, 269, 89-98
With catalytic amounts of 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) and hypochlorite/bromide as the regenerating oxidant in water, primary alcohol groups in glucans and derivatives thereof were rapidly and completely oxidised. For pyranosides, sel
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