Výsledky vyhledávání

Degradable Vinyl Copolymer Nanoparticles/Latexes by Aqueous Nitroxide-Mediated Polymerization-Induced Self-Assembly

Autor: Maëlle Lages, Noémie Gil, Paul Galanopoulo, Julie Mougin, Catherine Lefay, Yohann Guillaneuf, Muriel Lansalot, Franck D’Agosto, Julien Nicolas

Publikováno v: Macromolecules
Macromolecules, 2022, 55 (21), pp.9790-9801. ⟨10.1021/acs.macromol.2c01734⟩

International audience; The synthesis of degradable vinyl polymer nanoparticles/latexes in aqueous dispersed media is receiving much attention, particularly for biomedical applications and plastic pollution control, as it can circumvent the severe li

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::15656651d12c1fa1e008e73d88565e9b
https://doi.org/10.1021/acs.macromol.2c01734

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RAFT‐Mediated Emulsion Polymerization‐Induced Self‐Assembly for the Synthesis of Core‐Degradable Waterborne Particles

Autor: Paul Galanopoulo, Noémie Gil, Didier Gigmes, Catherine Lefay, Yohann Guillaneuf, Maëlle Lages, Julien Nicolas, Franck D'Agosto, Muriel Lansalot

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2023, ⟨10.1002/anie.202302093⟩

International audience

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::46dab765bb380ca1a3d9e0013a5a6a40
https://doi.org/10.1002/ange.202302093

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Degradable vinyl polymer particles by radical aqueous emulsion copolymerization of methyl methacrylate and 5,6-benzo-2-methylene-1,3-dioxepane

Autor: Paul Galanopoulo, Laura Sinniger, Noémie Gil, Didier Gigmes, Catherine Lefay, Yohann Guillaneuf, Maëlle Lages, Julien Nicolas, Franck D'Agosto, Muriel Lansalot

Publikováno v: Polymer Chemistry
Polymer Chemistry, In press, 14, pp.1224-1231. ⟨10.1039/D3PY00040K⟩

International audience; With an increasing interest in the synthesis of (bio)degradable polymers, the synthesis of (bio)degradable vinyl polymer particles is attracting growing attention. In this work, degradable poly(methyl methacrylate) (PMMA) part

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1b36dbd44410056b2e13a05844def57
https://hal.science/hal-04010853

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Degradable Polystyrene via the Cleavable Comonomer Approach

Autor: Noémie Gil, Baptiste Caron, Didier Siri, Julien Roche, Slim Hadiouch, Douriya Khedaioui, Stéphane Ranque, Carole Cassagne, Damien Montarnal, Didier Gigmes, Catherine Lefay, Yohann Guillaneuf

Publikováno v: Macromolecules
Macromolecules, 2022, 55 (15), pp.6680-6694. ⟨10.1021/acs.macromol.2c00651⟩

International audience; Polystyrene (PS) is a major commodity polymer widely used in various applications ranging from packaging to insulation thanks to its low cost, high stiffness, and transparency as well as its relatively high softening temperatu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c52f07aaf5d625cdc9599af93d5a4c05
https://hal-amu.archives-ouvertes.fr/hal-03953604

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Degradable Vinyl Polymer Nanoparticles/Latexes by Aqueous Nitroxide-Mediated Polymerization-Induced Self-Assembly

Autor: Maëlle Lages, Noémie Gil, Paul Galanopoulo, Julie Mougin, Catherine Lefay, Yohann Guillaneuf, Muriel Lansalot, Franck D'Agosto, Julien Nicolas

The synthesis of degradable vinyl polymer nanoparticles/latexes in aqueous dispersed media is receiving much attention, particularly for biomedical applications and plastic pollution control, as it can circumvent the severe limitations associated wit

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7754d104199ace01df410852c891615e
https://doi.org/10.26434/chemrxiv-2022-pf8k0

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Thionolactone as a Resin Additive to Prepare (Bio)degradable 3D Objects via VAT Photopolymerization

Autor: Noémie Gil, Constance Thomas, Rana Mhanna, Jessica Mauriello, Romain Maury, Benjamin Leuschel, Jean‐Pierre Malval, Jean‐Louis Clément, Didier Gigmes, Catherine Lefay, Olivier Soppera, Yohann Guillaneuf

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2022, 61 (18), pp.e202117700. ⟨10.1002/anie.202117700⟩

Three-dimensional (3D) printing and especially VAT photopolymerization leads to cross-linked materials with high thermal, chemical, and mechanical stability. Nevertheless, these properties are incompatible with requirements of degradability and re/up

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dbf9a28bd64095da22cf3fee854129dd
https://pubmed.ncbi.nlm.nih.gov/35128770

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One-Step Synthesis of Degradable Vinylic Polymer-Based Latexes via Aqueous Radical Emulsion Polymerization

Autor: Paul Galanopoulo, Noémie Gil, Didier Gigmes, Catherine Lefay, Yohann Guillaneuf, Maëlle Lages, Julien Nicolas, Muriel Lansalot, Franck D'Agosto

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2022, 61 (15), pp.e202117498. ⟨10.1002/anie.202117498⟩

International audience; Aqueous emulsion copolymerizations of dibenzo[c,e]oxepane-5-thione (DOT) were performed with n-butyl acrylate (BA), styrene (S) and a combination of both. In all cases, stable latexes were obtained in less than two hours under

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::113cdfad63e136f69a6d2cfc75bbf042
https://pubmed.ncbi.nlm.nih.gov/35100474

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Mechanistic Investigation of ε-Thiono-Caprolactone Radical Polymerization: An Interesting Tool to Insert Weak Bonds into Poly(vinyl esters)

Autor: Noémie Gil, Christopher M. Plummer, Pierre-Emmanuel Dufils, Yohann Guillaneuf, D. James Wilson, Catherine Lefay, Didier Gigmes

Publikováno v: ACS Applied Polymer Materials
ACS Applied Polymer Materials, American Chemical Society, 2021, 3 (6), pp.3264-3271. ⟨10.1021/acsapm.1c00569⟩
ACS Applied Polymer Materials, 2021, 3 (6), pp.3264-3271. ⟨10.1021/acsapm.1c00569⟩

International audience; The incorporation of heteroatoms into the backbone of commodity polymers prepared by radical polymerization is an elegant way to confer (bio)degradability to such materials. This could be achieved via the radical ring-opening

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e82e6ff0b058114266da6d5ab5234649
https://hal.archives-ouvertes.fr/hal-03357740/document

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Polyesters by a Radical Pathway: Rationalization of the Cyclic Ketene Acetal Efficiency

Autor: Didier Siri, Catherine Lefay, Yohann Guillaneuf, Christopher M. Plummer, Didier Gigmes, Noémie Gil, Antoine Tardy

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2020, 59 (34), pp.14517-14526. ⟨10.1002/anie.202005114⟩
Angewandte Chemie International Edition, 2020, 59 (34), pp.14517-14526. ⟨10.1002/anie.202005114⟩

Radical ring-opening polymerization (rROP) of cyclic ketene acetals (CKAs) combines the advantages of both ring-opening polymerization and radical polymerization thereby allowing the robust production of polyesters coupled with the mild polymerizatio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d584056bf62e3d99ae6e174a02521761
https://hal.archives-ouvertes.fr/hal-03004204/document

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