Výsledky vyhledávání - "Nina Gómez-Blanco"

Akademický článek

Microwave-assisted one-step synthesis of water-soluble manganese-carbon nanodot clusters

Autor: Nina Gomez-Blanco, Maurizio Prato

Publikováno v: Communications Chemistry, Vol 6, Iss 1, Pp 1-7 (2023)

Abstract Using metal coordination to assemble carbon nanodots (CND) into clusters can enhance their photophysical properties for applications in sensing and biomedicine. Water-soluble clusters of CNDs are prepared by one-step microwave synthesis star

Externí odkaz: https://doaj.org/article/6e408069451f427db9cab7f403d98b5e

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Mononuclear and tetranuclear palladacycles with terdentate [C,N,N] and [C,N,O] Schiff base ligands. C–H versus C–Br activation reactions

Autor: Antonio Rodríguez, Margarita López-Torres, Nina Gómez-Blanco, José M. Vila, Alberto Fernández, Jesús J. Fernández, Leticia Naya, Digna Vázquez-García

Publikováno v: Inorganica Chimica Acta. 370:89-97

Reaction of the Schiff base ligands 2-Br-4,5-(OCH2O)C 6H2C(H)NCH2CH2NMe2 (a) and 4,5-(OCH2CH2)C6H3C(H)NCH 2CH2NMe2 (b) with Pd(OAc)2 or K 2[PdCl4] leads to the mononuclear cyclometallated compounds [Pd{2-Br-4,5-(OCH2O)C6HC(H)NCH 2CH2NMe2-C6,N,N}(OCOM

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3401b9820c87e1e160d6a7cd6bb9fd15
https://doi.org/10.1016/j.ica.2011.01.027

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Cyclometallated Palladium Diphosphane Compounds Derived from the Chiral Ligand ( S )‐PhCH(Me)NMe 2 . Michael Addition Reactions to the Vinylidene Double Bond

Autor: Nina Gómez-Blanco, Antonio Rodríguez-Castro, Alberto Fernández, Jesús J. Fernández, Margarita López-Torres, José M. Vila, Roberto Mosteiro, Digna Vázquez-García

Publikováno v: European Journal of Inorganic Chemistry. 2011:1824-1832

Treatment of (S)-PhCH(Me)NMe2 (1) with palladium(II) acetate in toluene gave the dinuclear cyclometallated complex [Pd{(S)-C6H4CH(Me)NMe2-C2,N}(μ-OAc)]2 (2), inwhich the ligand is bonded to the palladium atom through the nitrogen phenyl carbon atoms

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a592cbd06da86bee0b2942de54bd8d41
https://doi.org/10.1002/ejic.201000873

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Reactivity of C(sp2)-Pd and C(sp3)-Pd bonded palladacycles with diphosphines. Crystal and molecular structure of the novel A-frame complex [{Pd[2,5-Me2C6H2C(H) N(2,4,6-Me3C6H2)-C6]}2(μ-Ph2PCH2PPh2)2(μ-Cl)][PF6]

Autor: Antonio Rodríguez, Nina Gómez-Blanco, Jesús J. Fernández, José M. Vila, Digna Vázquez-García, Carlos Viader, Alberto Fernández, Margarita López-Torres

Publikováno v: Journal of Organometallic Chemistry. 696:764-771

Treatment of the halogen-bridged complexes [Pd{2,5-Me2C6H2C(H) N(2,4,6-Me3C6H2)-C6,N}(μ-X)]2 (1a, X = Cl; 2a, X = Br) with the tertiary diphosphine Ph2PCH2PPh2 (dppm), regardless of the molar ratio used, gave a mixture of two complexes: [Pd{2,5-Me2C

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b352bb5d0d26a4c783375e67a1fe6317
https://doi.org/10.1016/j.jorganchem.2010.09.071

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Versatile Behavior of the Schiff Base Ligand 2,5-Me2C6H3C(H)═N(2,4,6-Me3C6H2) toward Cyclometalation Reactions: C(sp2,phenyl)−H vs C(sp3,methyl)−H Activation

Autor: Carlos Viader, Nina Gómez-Blanco, José M. Vila, Antonio Rodríguez, Jesús J. Fernández, Digna Vázquez-García, Margarita López-Torres, Alberto Fernández

Publikováno v: Organometallics. 29:3303-3307

Treatment of the Schiff base ligand a with palladium(II) acetate in toluene gave 1a, with metalation of an aromatic phenyl carbon atom. Reaction at room temperature gave the trinuclear complex 4a. Treatment of a with palladium(II) acetate in refluxin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f7fa5ef39bcd64de57bb6b71e4d85216
https://doi.org/10.1021/om100238w

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Synthesis and characterization of new heterocyclic Schiff base palladacycles: Ring activation through N-oxide formation

Autor: Antonio Rodríguez, Digna Vázquez-García, Margarita López-Torres, Nina Gómez-Blanco, Alberto Fernández, Jesús J. Fernández, José M. Vila

Publikováno v: Polyhedron. 28:3607-3613

Reaction of the Schiff base ligand derived from 4-pyridinecarboxaldehyde NC5H4C(H) N[2′,4′,6′-(CH3)C6H2], (1), with palladium(II) acetate in toluene at 60 °C for 24 h gave [Pd{NC5H4C(H) N[2′,4′,6′-(CH3)C6H2]}2(OCOCH3)2], (2), with two li

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dabd8a0629a4fe273b1db7ecc88e7009
https://doi.org/10.1016/j.poly.2009.07.058

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Synthesis and reactivity of new functionalized Pd(II) cyclometallated complexes with boronic esters

Autor: Antonio Rodríguez, Jesús J. Fernández, Alberto Fernández, Nina Gómez-Blanco, Margarita López-Torres, José M. Vila, Digna Vázquez-García

Publikováno v: Journal of Organometallic Chemistry. 694:3597-3607

Treatment of the functionalized Schiff base ligands with boronic esters 1a, 1b, 1c and 1d with palladium (II) acetate in toluene gave the polynuclear cyclometallated complexes 2a, 2b, 2c and 2d, respectively, as air-stable solids, with the ligand as

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bb55103f021e110b42a7f10234d0b841
https://doi.org/10.1016/j.jorganchem.2009.07.009

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Seeking new metalloligands: Synthesis and reactivity of palladacycles with pyridine and pyrimidine rings

Autor: Nina Gómez-Blanco, José M. Vila, Digna Vázquez-García, Jesús J. Fernández, Alberto Fernández, Margarita López-Torres

Publikováno v: Polyhedron. 28:2679-2683

Treatment of the Schiff base ligands 4-(NC5H4)C6H4C(H){double bond, long}N[2′-(OH)C6H4] (a), 3,5-(N2C4H3)C6H4C(H){double bond, long}N[2′-(OH)-C6H4] (b) and 3,5-(N2C4H3)C6H4C(H) {double bond, long}N[2′-(OH)-5′-tBuC6H3] (c) with palladium (II)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::457805dba753f25a233fe842c07871b4
https://doi.org/10.1016/j.poly.2009.05.005

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Cyclometallated [C,N,O] Complexes as Metalloligands: Synthesis and Structural Characterisation of New Di‐, Tri‐, Tetra‐ and Pentanuclear Heterometallic Complexes

Autor: Nina Gómez-Blanco, Margarita López-Torres, Alberto Fernández, José M. Vila, Digna Vázquez-García, Jesús J. Fernández

Publikováno v: European Journal of Inorganic Chemistry. 2009:3071-3083

Reaction of the Schiff-base ligands 4-(4-NC 5 H 4 )C 6 H 4 C-(H)=N(C 6 H 3 0H-2-tBu-5) (a) and (4-NC 5 H 4 )C(H)=N(C 6 H 3 -OH-2-tBu-5) (b) with palladium(II) acetate in toluene at 60 °C gave the tetranuclear orthometallated palladium complexes 1a a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8dead05bace8ae88ee6b66b8a2a00d81
https://doi.org/10.1002/ejic.200900052

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Synthesis, characterization and crystal structures of cyclometallated palladium (II) compounds containing difunctional ligands with [P,P], [As,As], [N,N], [P,As], [P,N] and [P,O] donor atoms

Autor: José M. Vila, Raquel Ares, Alberto Fernández, Nina Gómez-Blanco, Digna Vázquez-García, Margarita López-Torres, Jesús J. Fernández

Publikováno v: Journal of Organometallic Chemistry. 693:3655-3667

Treatment of the chloro-bridged dinuclear complex [Pd{3,4-(MeO) 2 C 6 H 2 C(H) N(Cy)- C 6, N }(μ-Cl)] 2 ( 1 ) with homobidentate [ P , P ], [ As , As ], [ N , N ], and heterobidentate [ P , As ], [ P , N ] ligands in a 1:1 molar ratio gave the dinuc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1f21511d8f37dfddd8bbe9681131b6f3
https://doi.org/10.1016/j.jorganchem.2008.08.023

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