Zobrazeno 1 - 10
of 21
pro vyhledávání: '"Nilusha, Priyadarshani"'
Autor:
Alaa A. Oughli, Adrian Ruff, Nilusha Priyadarshani Boralugodage, Patricia Rodríguez-Maciá, Nicolas Plumeré, Wolfgang Lubitz, Wendy J. Shaw, Wolfgang Schuhmann, Olaf Rüdiger
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
Bio-inspired Ni-based molecular catalysts are efficient for H2 oxidation, but are suffering from the poor stability in the presence of O2. Here, the authors develop a strategy to boost greatly their stability by dispersing them in a hydrophobic and r
Externí odkaz:
https://doaj.org/article/5427622b542942a88eba3165c11305a9
Autor:
Nilusha, Priyadarshani, Yannan, Liang, Jakkrit, Suriboot, Hassan S, Bazzi, David E, Bergbreiter
Publikováno v:
ACS macro letters. 2(7)
Polyisobutylene (PIB)-bound ruthenium bipyridine [Ru(PIB-bpy)
Autor:
Wendy J. Shaw, J. Timothy Bays, Geoffrey M. Chambers, Aaron P. Walsh, Nilusha Priyadarshani, Joseph A. Laureanti, Sheri Lense, John C. Linehan, Sriram Katipamula
Publikováno v:
Faraday Discussions. 215:123-140
To explore the influence of a biologically inspired second and outer coordination sphere on Rh-bis(diphosphine) CO2 hydrogenation catalysts, a series of five complexes were prepared by varying the substituents on the pendant amine in the P(Et)2CH2NRC
Autor:
Aaron P, Walsh, Joseph A, Laureanti, Sriram, Katipamula, Geoffrey M, Chambers, Nilusha, Priyadarshani, Sheri, Lense, J Timothy, Bays, John C, Linehan, Wendy J, Shaw
Publikováno v:
Faraday discussions. 215
To explore the influence of a biologically inspired second and outer coordination sphere on Rh-bis(diphosphine) CO2 hydrogenation catalysts, a series of five complexes were prepared by varying the substituents on the pendant amine in the P(Et)2CH2NRC
Autor:
Garry W. Buchko, Arnab Dutta, Wendy J. Shaw, Nilusha Priyadarshani Boralugodage, Rajith Jayasingha Arachchige
Publikováno v:
Catalysis Science & Technology. 7:1108-1121
Amino acids and peptides have been shown to have a significant influence on the H2 production and oxidation reactivity of Ni(PR2NR′2)2, where PR2NR′2 = 1,5-diaza-3,7-diphosphacyclooctane, R is either phenyl (Ph) or cyclohexyl (Cy), and R′ is ei
Autor:
Nilusha Priyadarshani, Wendy J. Shaw, Arnab Dutta, Wolfgang Lubitz, Patricia Rodríguez-Maciá, Olaf Rüdiger, Claudia Weidenthaler
Publikováno v:
Electroanalysis. 28:2452-2458
Hydrogenases are a diverse group of metalloenzymes which catalyze the reversible conversion between molecular hydrogen and protons at high rates. The catalytic activity of these enzymes does not require overpotential because their active site has bee
Autor:
Wendy J. Shaw, Nilusha Priyadarshani, Arnab Dutta, Molly O'Hagan, Bojana Ginovska, Simone Raugei, Garry W. Buchko
Publikováno v:
ACS Catalysis. 6:6037-6049
Inspired by the contribution of the protein scaffold to the efficiency with which enzymes function, we used outer coordination sphere features to develop a molecular electrocatalyst for the reversible production/oxidation of H2 at 25 °C: [Ni(PCy2NPh
Autor:
Olaf Rüdiger, Wolfgang Schuhmann, Nilusha Priyadarshani Boralugodage, Patricia Rodríguez-Maciá, Adrian Ruff, Alaa A. Oughli, Nicolas Plumeré, Wolfgang Lubitz, Wendy J. Shaw
Publikováno v:
Nature Communications
Nature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
Nature Communications, Vol 9, Iss 1, Pp 1-6 (2018)
The Ni(P2N2)2 catalysts are among the most efficient non-noble-metal based molecular catalysts for H2 cycling. However, these catalysts are O2 sensitive and lack long term stability under operating conditions. Here, we show that in a redox silent pol
Autor:
J. Timothy Bays, Deanna L. Miller, Wendy J. Shaw, John C. Linehan, Nilusha Priyadarshani, Matthew S. Jeletic, Elliot B. Hulley
Publikováno v:
ACS Catalysis. 4:3663-3670
A series of [Rh(PCH2XRCH2P)2]+ complexes was prepared to investigate second and outer coordination sphere effects on CO2 hydrogenation catalysis, where X is CH2 (dppp) or X–R is N–CH3, N–CH2COOH (glycine), N–CH2COOCH3 (Gly-OMe), or N–CH2C(O
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