Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Nikolay V. Kireev"'
The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes
Autor:
Elena S. Osipova, Sergey A. Kovalenko, Ekaterina S. Gulyaeva, Nikolay V. Kireev, Alexander A. Pavlov, Oleg A. Filippov, Anastasia A. Danshina, Dmitry A. Valyaev, Yves Canac, Elena S. Shubina, Natalia V. Belkova
Publikováno v:
Molecules, Vol 28, Iss 8, p 3368 (2023)
Acid-base characteristics (acidity, pKa, and hydricity, ΔG°H− or kH−) of metal hydride complexes could be a helpful value for forecasting their activity in various catalytic reactions. Polarity of the M–H bond may change radically at the stag
Externí odkaz:
https://doaj.org/article/e9243d1afd10415b9193ede303ec0ee6
Autor:
Nikolay V. Kireev, Elena S. Shubina, Natalia V. Belkova, Elvira I. Musina, Alexander A. Pavlov, Konstantin L. Ivanov, Alexandra V. Yurkovskaya, Alexey S. Kiryutin, Andrey A. Karasik
Publikováno v:
European Journal of Inorganic Chemistry. 2021:4265-4272
Autor:
Elena S. Osipova, Ekaterina S. Gulyaeva, Nikolay V. Kireev, Sergey A. Kovalenko, Christian Bijani, Yves Canac, Dmitry A. Valyaev, Oleg A. Filippov, Natalia V. Belkova, Elena S. Shubina
Publikováno v:
Chemical Communications
Chemical Communications, 2022, 58 (32), pp.5017-5020. ⟨10.1039/d2cc00999d⟩
Chemical Communications, 2022, 58 (32), pp.5017-5020. ⟨10.1039/d2cc00999d⟩
International audience; Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of apparently simple reactions between Mn(I) complex fac-[(dppm)Mn(CO)3H] and Lewis acids (LA = Ph3C+, B(C6F5)3) involving t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f77e4a7e8d36bb1bc43fdd51fdc8f455
https://hal.science/hal-03652224/document
https://hal.science/hal-03652224/document
Autor:
Nikolay V, Kireev, Oleg A, Filippov, Ekaterina S, Gulyaeva, Elena S, Shubina, Laure, Vendier, Yves, Canac, Jean-Baptiste, Sortais, Noël, Lugan, Dmitry A, Valyaev
Publikováno v:
Chemical communications (Cambridge, England). 56(14)
Deprotonation of fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3Br] (R = H, Me, Ph) produces the corresponding diphosphinomethanide derivatives fac-[(κ3P,C,P-Ph2PC(R)PPh2)Mn(CO)3], which are prone to activate H2 to form the hydride complexes fac-[(κ2P,P-Ph2PCH(
Autor:
Alexander A. Pavlov, Oleg A. Filippov, Lina M. Epstein, Nikolay V. Kireev, Natalia V. Belkova, Victor D. Makhaev, V. P. Dyadchenko, Elena S. Shubina
Publikováno v:
Inorganic Chemistry. 57:1656-1664
The interaction of trans-W(N2)2(dppe)2 (1; dppe = 1,2-bis(diphenylphosphino)ethane) with relatively weak acids (p-nitrophenol, fluorinated alcohols, CF3COOH) was studied by means of variable temperature IR and NMR spectroscopy and complemented by DFT
Autor:
Alexandra V. Yurkovskaya, Elvira I. Musina, Konstantin L. Ivanov, Alexander A. Pavlov, Alexey S. Kiryutin, Elena S. Shubina, Nikolay V. Kireev, Natalia V. Belkova, Andrey A. Karasik
Publikováno v:
European Journal of Inorganic Chemistry. 2021:4238-4238
Autor:
Nikolay V, Kireev, Oleg A, Filippov, Alexander A, Pavlov, Lina M, Epstein, Victor D, Makhaev, Victor P, Dyadchenko, Elena S, Shubina, Natalia V, Belkova
Publikováno v:
Inorganic chemistry. 57(3)
The interaction of trans-W(N