Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Nikola S. Lambic"'
Autor:
Jonathan Schaefer, Hua Zhou, Eryn Lee, Nikola S. Lambic, Gursu Culcu, Matthew W. Holtcamp, Francis C. Rix, Tzu-Pin Lin
Publikováno v:
ACS Catalysis. 12:11870-11885
Autor:
Carlos R. López-Barrón, Nikola S. Lambic, Joseph A. Throckmorton, Jonathan J. Schaefer, Avery Smith, Frank N. Raushel, Tzu-Pin Lin
Publikováno v:
Macromolecules. 55:284-296
Publikováno v:
Organometallics. 39:388-396
Direct insertion of CO and isocyanides, RNC, into Re–R bonds results in high-oxidation-state acyl and iminoacyl complexes that can be treated with an electrophile to generate rare examples of rheni...
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(18)
A method for the preparation of nitridorhenium(V) complexes of the form (SSS)Re(N)(L) (where SSS = 2-mercaptoethylsulfide and L = PPh3 and t-BuNC) has been described. These complexes react with Lewis acids allowing for the isolation of adducts. The l
Publikováno v:
Dalton Transactions. 47:758-768
The synthesis of (PNP)Re(N)X (PNP = [2-P(CHMe2)2-4-MeC6H3]2N, X = Cl and Me) complexes is described. The methylnitridorhenium complex 3 was found to react differently with CO and isocyanides, leading to the isolation of a Re(v) acyl complex 4 and an
Publikováno v:
Organometallics. 36:2042-2051
In this work we show that classic coordination of the oxo group in an oxorhenium hydride complex to M(C6F5)3 (M = Al, B) leads to dramatic increases in the rate of migratory olefin insertion. Combined experimental and computational studies have been
Publikováno v:
ACS Catalysis. 7:1170-1180
The steric and electronic demands of the catalytic olefin hydrogenation of tert-butylethylene with oxorhenium/Lewis acid FLPs were evaluated. The sterics of the ligand were altered by installing bulkier isopropyl groups in the 2,6-positions of the di
Publikováno v:
Organometallics. 35:3060-3068
Computational studies (M06) have been performed in synergy with experimental studies to show that the thermodynamics for insertion of CO into an oxorhenium–hydride bond to form a formyl ligand is favorable despite conventional wisdom to the contrar
Publikováno v:
Organometallics. 35:2822-2829
Several oxorhenium hydride complexes with chelating diamidopyridine (DAP), diamidoamine (DAAm), and 2-mercaptoethyl sulfide (SSS) groups have been isolated and characterized. Adduct formation is observed when the DAP complex 1a is treated with the Le
Autor:
Elon A. Ison, Cody M. Perry, Roger D. Sommer, Khalil A. Abboud, Sriparna Mukherjee, Elena Jakubikova, Daniel A. Frasco, Nikola S. Lambic
Publikováno v:
Organometallics. 35:2435-2445
Combined experimental and computational studies have revealed factors that influence the nondirected C–H activation in Cp*Ir complexes that contain carboxylate ligands. A two-step acetate-assisted pathway was shown to be operational where the first