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pro vyhledávání: '"Niklas Radhoff"'
Autor:
Niklas Radhoff, Armido Studer
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-10 (2022)
The α-arylation of amides via aryl migration has attracted considerable interest in recent years. Here, the authors report a method for the preparation of bulky α-quaternary amides via a polar-radical crossover enolate oxidation-aryl migration casc
Externí odkaz:
https://doaj.org/article/e035ca43aa4f40e3b70e6d5d56e48109
Publikováno v:
Angewandte Chemie.
Autor:
Armido Studer, Niklas Radhoff
Publikováno v:
Angewandte Chemie. 133:3603-3608
Autor:
Niklas, Radhoff, Armido, Studer
Publikováno v:
Nature communications. 13(1)
The arylation of carboxylic acid derivatives via Smiles rearrangement has gained great interest in recent years. Both radical and ionic approaches, as well as radical-polar crossover concepts, have been developed. In contrast, a reversed polar-radica
Autor:
Niklas Radhoff, Armido Studer
Publikováno v:
Angewandte Chemie (International Ed. in English)
Angewandte Chemie International Edition
Angewandte Chemie International Edition
α‐C−H arylation of N‐alkylamides using 2‐iodoarylsulfonyl radical translocating arylating (RTA) groups is reported. The method allows the construction of α‐quaternary carbon centers in amides. Various mono‐ and disubstituted RTA‐group