Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Niklas B. Thompson"'
Publikováno v:
IUCrJ, Vol 11, Iss 3, Pp 423-433 (2024)
Appreciating that the role of the solute–solvent and other outer-sphere interactions is essential for understanding chemistry and chemical dynamics in solution, experimental approaches are needed to address the structural consequences of these inte
Externí odkaz:
https://doaj.org/article/53c3ccb9a1504795b344013632a06317
Autor:
Justin M. Hoffman, Niklas B. Thompson, Olaf Borkiewicz, Xiang He, Samuel Amsterdam, Zhu-lin Xie, Aaron Taggart, Karen L. Mulfort, Alex B. F. Martinson, Lin X. Chen, Uta Ruett, David M. Tiede
Publikováno v:
IUCrJ, Vol 11, Iss 1, Pp 120-128 (2024)
The application of grazing-incidence total X-ray scattering (GITXS) for pair distribution function (PDF) analysis using >50 keV X-rays from synchrotron light sources has created new opportunities for structural characterization of supported thin film
Externí odkaz:
https://doaj.org/article/c928735c9517434d99c032ebff4ed28d
Autor:
Alex McSkimming, Niklas B. Thompson
Publikováno v:
Inorganic Chemistry. 61:12318-12326
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::89e9c138ebbc69a7d1fa52ead97720a9
https://doi.org/10.1021/acs.inorgchem.2c01656
https://doi.org/10.1021/acs.inorgchem.2c01656
Publikováno v:
Proceedings of the National Academy of Sciences. 120
Nature employs weak-field metalloclusters to support a wide range of biological processes. The most ubiquitous metalloclusters are the cuboidal Fe–S clusters, which are comprised of Fe sites with locally high-spin electronic configurations. Such co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::02665a84f4053565cff5eb3da3e29b84
https://doi.org/10.1073/pnas.2210528120
https://doi.org/10.1073/pnas.2210528120
Publikováno v:
Journal of the American Chemical Society. 144(20)
Although biological iron-sulfur (Fe-S) clusters perform some of the most difficult redox reactions in nature, they are thought to be composed exclusively of Fe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5bee2fd9a6372baf7d9757da282375b3
https://pubmed.ncbi.nlm.nih.gov/35575703
https://pubmed.ncbi.nlm.nih.gov/35575703
Autor:
Ethan A. Hill, Niklas B. Thompson, Margaret L. Kelty, W. Hill Harman, Laura A. Essex, Alex McSkimming
Publikováno v:
Organometallics. 39:2545-2552
Transition-metal arene complexes are important species in catalysis and arene functionalization. Certain electron-rich metal fragments are capable of binding arenes across two adjacent carbon atoms, inducing significant dearomatization through strong
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d05c377897c278da044dbde3e871d868
https://doi.org/10.1021/acs.organomet.0c00340
https://doi.org/10.1021/acs.organomet.0c00340
Publikováno v:
Journal of the American Chemical Society. 141:13330-13335
Although alkyl complexes of [Fe4S4] clusters have been invoked as intermediates in a number of enzymatic reactions, obtaining a detailed understanding of their reactivity patterns and electronic structures has been difficult owing to their transient
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2f26c8caef3051ff344c186983dcc90a
https://doi.org/10.1021/jacs.9b06975
https://doi.org/10.1021/jacs.9b06975
Publikováno v:
Angewandte Chemie. 131:6286-6290
Species with 2‐center, 3‐electron (2c/3e−) σ bonds are of interest owing to their fascinating electronic structures and potential for interesting reactivity patterns. Report here is the synthesis and characterization of a pair of zerovalent (d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::536046850f9a528d3459deea7789f2ab
https://doi.org/10.1002/ange.201814206
https://doi.org/10.1002/ange.201814206
Publikováno v:
PMC
J Am Chem Soc
J Am Chem Soc
Copyright © 2020 American Chemical Society. Alkyl-ligated iron-sulfur clusters in the [Fe4S4]3+ charge state have been proposed as short-lived intermediates in a number of enzymatic reactions. To better understand the properties of these intermediat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8c46bae6f42c2cfb018edef261bfe684
https://hdl.handle.net/1721.1/132591
https://hdl.handle.net/1721.1/132591
Publikováno v:
Journal of the American Chemical Society. 139:15312-15315
Terminal iron nitrides (Fe≡N) have been proposed as intermediates of (bio)catalytic nitrogen fixation, yet experimental evidence to support this hypothesis has been lacking. In particular, no prior synthetic examples of terminal Fe≡N species have
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3bfd6e5ea6df092ae47bcfca9d3aadd8
https://doi.org/10.1021/jacs.7b09364
https://doi.org/10.1021/jacs.7b09364